Results 191 to 200 of about 46,982 (304)

High‐Energy‐Density Redox Flow Batteries: Mechanisms, Design Strategies, and Recent Progress

open access: yesChemistry – A European Journal, EarlyView.
ABSTRACT The inherent intermittency of energy sources such as solar and wind power hinders the transition to renewable energy, necessitating advanced energy storage solutions. Enhancing energy density is crucial for lowering system costs and enabling large‐scale deployment.
Xiaolian Zhao   +8 more
wiley   +1 more source

Iridium Complexes of a Triazole‐Derived Pincer Ligand: Synthesis, Reactivity, and Transfer Dehydrogenation Catalysis

open access: yesChemistry – A European Journal, EarlyView.
Ir pincer complexes bearing a triazole architecture in the pincer backbone and O‐ancillary chelating ligands are presented. These were employed in the catalytic transfer dehydrogenation of alkanes as well as of saturated heterocycles. Reactivity of these complexes with silver salts and Lewis acids produced various cationic iridium complexes.
Jesvita Cardozo   +5 more
wiley   +1 more source

Synthesis, in-vitro, <i>in-silico</i>, and global DNA methylation studies of curcumin-benzoquinone analog in triple-negative breast cancer (TNBC) cells. [PDF]

open access: yesToxicol Res (Camb)
Günçer B   +10 more
europepmc   +1 more source

Self‐Immolative Gels: Programmable Degradation Using Self‐Immolative Linkers and Polymers

open access: yesChemistry – A European Journal, EarlyView.
Self‐immolative linkers and polymers undergo bond‐cleaving reaction cascades in response to specific stimuli. Their incorporation into gels can be harnessed to release cargo, induce property changes, or trigger degradation in a highly controlled manner. These functions can be employed in applications such as sensing and drug delivery.
Chuanfeng Li, Elizabeth R. Gillies
wiley   +1 more source

When Light Challenges Heat: Mechanistic Insights Into a Reaction Competing With Cadogan Cyclisation in Nitro‐Perylenediimides

open access: yesChemistry – A European Journal, EarlyView.
Visible‐light irradiation of nitro‐perylenediimide in the presence of triphenylphosphine reveals an unexpected pathway competing with the classical Cadogan cyclization. Mechanistic investigations uncover the rapid and selective formation of bay‐functionalized 1‐iminophosphorane‐12‐hydroxy perylenediimide derivatives.
Manuel Pedrón Laserna   +2 more
wiley   +1 more source

Hydroquinone Oxidation by Redox‐active Guanidines and Thioguanidines: Faster Conversion to High‐Potential Than to Low‐Potential Quinones

open access: yesChemistry – A European Journal, EarlyView.
New redox‐active oligothioguanidines are developed and used in dehydrogenative P–P coupling reactions and hydroquinone oxidations. Tetrathioguanidino‐ and tetraguanidinobenzenes oxidize high‐potential halogenated hydroquinones faster than relatively low‐potential hydroquinone.
Ute Wild   +4 more
wiley   +1 more source

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