Copper-catalysed rearrangement of 4-substituted-2,3-1H-benzoxazine-1-thiones
4-Substituted-2,3-1H-benzoxazine-1-thiones were prepared by the treatment of the corresponding benzoxazine-1-ones with P2S5. The thermal rearrangement of 4-substituted-2,3-1H-benzoxazine-1-thiones, catalysed by metallic copper, yielded 4-substituted-2,3 ...
Guner, SELAHADDİN, Agirbas, H
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Thermal Stability of Allyl-Functional Phthalonitriles-Containing Benzoxazine/Bismaleimide Copolymers and Their Improved Mechanical Properties [PDF]
Mingzhen Xu +5 more
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Amino-functional benzoxazine monomers have been successfully prepared. Several routes have been applied to incorporate amino group into benzoxazine structure.
Agag, Tarek +6 more
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Chiral Bidentate (Phosphinophenyl)benzoxazine Ligands in Asymmetric Catalysis
The new chiral bidentate (phosphinoaryl)benzoxazine ligands 2 were applied in asymmetric catalysis. Rhodium and copper complexes catalyzed the hydrosilylation of acetophenone and [4+2] cycloadditions with moderate enantioselectivity.
Radkowski, Karin +6 more
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Synthesis and Fungicidal Activity of 1-(Carbamoylmethyl)-2-aryl-3,1-benzoxazines [PDF]
Zi-Long Tang +4 more
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Intrinsic self‐initiating thermal ring‐opening polymerization of 1,3‐benzoxazines without the influence of impurities using very high purity crystals [PDF]
Lu Han +4 more
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Meta-phenylenediamine formaldehyde oligomer: A new accelerator for benzoxazine resin
Meta-phenylenediamine formaldehyde oligomer is prepared and used as an accelerator for benzoxazine resin. The structure of the oligomer is characterized by Fourier transform infrared spectroscopy and 1H nuclear magnetic resonance spectroscopy.
Yingxin Chen +11 more
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Constructing a gradient modulus interfacial layer on the surface of hydrotalcite enhances the interfacial properties of hydrotalcite/benzoxazine composites [PDF]
Lu Zhang +6 more
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Synthesis and characterization of chalcone-containing benzoxazine
本論文使用含有chalcone結構之雙酚單體,成功製備出雙官能的氧代氮代苯并環己烷(Benzoxazine)單體(2)。將合成之 Benzoxazine 單體以紫外光照射,探討其雙鍵因受光激發進行[2+2]環加成(cycloaddition)反應及其結構變化。 此外,為了瞭解光交聯機制對於整體熱性質與機械性質的影響,將照光後的Benzoxazine 單體(2)進行加熱固化,使雙鍵進行環加成反應後,再升溫固化使得Benzoxazine開環,進而得到交聯之網狀結構,因此在材料測試方面,由於其交聯密度的提升 ...
簡君愷, Chun-Kai Chien
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