Synthesis of germanium dioxide nanoparticles in benzyl alcohols – a comparison
The surfactant-free synthesis of β-phase germanium dioxide nanoparticles in ortho-methoxy benzyl alcohol and benzyl alcohol has been reported. Characterisation of the hexagonal β-GeO2 crystals, which involves powder X-ray diffraction, nitrogen adsorption
Kitschke Philipp +3 more
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Asymmetric preparation of antifungal 1-(4 -chlorophenyl)-1-cyclopropyl methanol and 1-(4 -chlorophenyl)-2-phenylethanol. Study of the detoxification mechanism by Botrytis cinerea [PDF]
Chiral alcohols are important as bioactive compounds or as precursors to such molecules. On the basis of the different antifungal properties of the enantiopure alcohol derivatives of 4-chlorophenyl cyclopropyl ketone and benzyl 4-chlorophenyl ketone ...
Aleu Casatejada, Josefina +4 more
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Electrocarboxylation in supercritical CO2 and CO2-expanded liquids [PDF]
In this study, the electrocarboxylation of benzyl chloride in pressurized CO2, or pressurized mixtures of dimethylformamide (DMF) and CO2, was investigated in order to synthesize phenylacetic acid.
Camy, Séverine +3 more
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Polyoxometalate-intercalated layered double hydroxides as efficient and recyclable bi-functional catalysts for cascade reactions [PDF]
The polyoxometalate (POM) intercalated-layered double hydroxides (LDHs) have been widely used as heterogeneous catalysts. However, the application of POM-LDHs as bi-functional catalysts for cascade reaction has seldom been studied comparing with the ...
Angelescu +41 more
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Enantioselective synthesis of (+)-petromyroxol, enabled by rhodium-catalyzed denitrogenation and rearrangement of a 1-sulfonyl-1,2,3-triazole [PDF]
Petromyroxol is a non-racemic mixture of enantiomeric oxylipids isolated from water conditioned with larval sea lamprey. The (+)-antipode exhibits interesting biological properties but only 1 mg was isolated from >100000 L of water.
Boyer, Alistair
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Honey volatiles as a fingerprint for botanical origin: a review on their occurrence on monofloral honeys [PDF]
Honeys have specific organoleptic characteristics, with nutritional and health benefits, being highly appreciated by consumers, not only in food but also in the pharmaceutical and cosmetic industries. Honey composition varies between regions according to
Figueiredo, Ana Cristina +3 more
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Predicting the substrate specificity of a glycosyltransferase implicated in the production of phenolic volatiles in tomato fruit [PDF]
The volatile compounds that constitute the fruit aroma of ripe tomato (Solanum lycopersicum) are often sequestered in glycosylated form. A homology-based screen was used to identify the gene SlUGT5, which is a member of UDP-glycosyltransferase 72 family ...
Alba +41 more
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Synthesis and viscosity behavior of poly(γ-p-biphenylmethyl-L-glutamate) in benzene/dichloroacetic acid mixtures, a comparison with poly(γ-benzyl-L-glutamate) [PDF]
The synthesis of poly(γ-p-biphenylmethyl-L-glutamate), PBPLG, (poly{L-imino-1-[2-(4-biphenylylmethoxycarbonyl)ethyl]-2-oxoethylene}), (1d) is described. The viscosity behavior of this polymer in benzene/dichloroacetic acid mixtures (c=0,2.10 -3 - 1,4.10 -
Bantjes, Adriaan +4 more
core +3 more sources
Flavorings and volatile biologically active substances, used by humans for various purposes, may potentially have fumigating, repellent, or attractive effects on various species of anthropod storage pests.
Titov Oleksii, Brygadyrenko Viktor
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Photocatalytic performance of SiO2@TiO2 spheres in selective conversion of oxidation of benzyl alcohol to benzaldehyde and reduction of nitrobenzene to aniline [PDF]
Selective photocatalytic oxidation of benzyl alcohol to benzaldehyde and reduction of nitrobenzene to aniline reactions are investigated by using SiO2@TiO2 spheres produced in a simple route using chitosan as a template.
BRUNO C.B. SALGADO, ANTONINHO VALENTINI
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