Results 231 to 240 of about 148,119 (340)

Ghost effect from Boltzmann theory

open access: yesCommunications on Pure and Applied Mathematics, EarlyView.
Abstract Taking place naturally in a gas subject to a given wall temperature distribution, the “ghost effect” exhibits a rare kinetic effect beyond the prediction of classical fluid theory and Fourier law in such a classical problem in physics. As the Knudsen number ε$\varepsilon$ goes to zero, the finite variation of temperature in the bulk is ...
Raffaele Esposito   +3 more
wiley   +1 more source

Probing the Hybrid σ/π‐Holes in sp2‐Hybridized Chalcogen Bond Donors and their Complexes with Ammonia

open access: yesChemPhysChem, EarlyView.
A double‐bonded chalcogen bond donor exhibits both a σ‐hole and a π‐hole on the same atom. These unique σ/π‐holes can be tuned based on molecular composition to be directional or semidirectional depending on the donor–acceptor bonding configuration, which differs from the behavior of other electropositive holes.
Kirk A. French   +3 more
wiley   +1 more source

Geometric Theory Predicts Bifurcations in Minimal Wiring Cost Trees in Biology Are Flat

open access: gold, 2012
Yihwa Kim   +4 more
openalex   +2 more sources

Spontaneous Mirror‐Symmetry Breaking Destabilizes Racemates: A Route to Homochirality and Reversed Chemical Selectivity

open access: yesChemPhysChem, EarlyView.
Reaction networks yielding spontaneous mirror‐symmetry breaking (SMSB) are revisited. All include a first‐order enantioselective autocatalysis, which, on its own, is unable to lead to SMSB. The coupling with the so‐called ancillary reactions (racemization, mutual inhibition, etc.) makes the racemic state unstable.
Josep M. Ribó   +2 more
wiley   +1 more source

Solvent Effects on the Selectivity of Ambimodal Dipolar/Diels–Alder Cycloadditions: A Study Using Explicit Solvation Models

open access: yesChemPhysChem, EarlyView.
Post‐transition state bifurcation in the reaction of 2‐aminoacrolein with 1,3‐butadiene is investigated using explicit solvation (up to 45 water molecules). GFN2‐xTB dynamics reveal strong solvent‐size effects on branching to (4 + 2) and (4 + 3) cycloadducts via an ambimodal transition state.
Hayato Matsubuchi   +6 more
wiley   +1 more source

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