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Energy & Fuels, 2014
The fuel properties of fast pyrolysis bio-oils differ significantly from those of fossil fuels. As transportation fuel, bio-oil is not suitable without upgrading because of its relatively low energy content, high water content, acidity, and poor storage stability. Upgrading of bio-oil has usually been done by treating the whole oil in a reactor.
Kuoppala, Eeva +5 more
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The fuel properties of fast pyrolysis bio-oils differ significantly from those of fossil fuels. As transportation fuel, bio-oil is not suitable without upgrading because of its relatively low energy content, high water content, acidity, and poor storage stability. Upgrading of bio-oil has usually been done by treating the whole oil in a reactor.
Kuoppala, Eeva +5 more
openaire +1 more source
2017
Stability of fast pyrolysis bio-oils is a complex phenomenon, especially as numerous compounds with different reactivities are involved. Acid-catalysed condensation and polymerization reactions of carbonyl compounds and reactive lignin-derived radical species take place which increase the share of water-insoluble compounds, average molecular weight and
Oasmaa, Anja
+6 more sources
Stability of fast pyrolysis bio-oils is a complex phenomenon, especially as numerous compounds with different reactivities are involved. Acid-catalysed condensation and polymerization reactions of carbonyl compounds and reactive lignin-derived radical species take place which increase the share of water-insoluble compounds, average molecular weight and
Oasmaa, Anja
+6 more sources
Transformation of Bio‐oil into BTX by Bio‐oil Catalytic Cracking
Chinese Journal of Chemical Physics, 2013Production of benzene, toluene and xylenes (BTX) from bio‐oil can provide basic feedstocks for the petrochemical industry. Catalytic conversion of bio‐oil into BTX was performed by using different pore characteristics zeolites (HZSM‐5, HY‐zeolite, and MCM‐41).
Jiu‐fang Zhu +2 more
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Ternary Phase Diagram of Water/Bio-Oil/Organic Solvent for Bio-Oil Fractionation
Energy & Fuels, 2020Separating bio-oil by fractionation with different chemical compositions is a critical step to refine these oils and obtain high-value products.
Yinglei Han +4 more
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2018
The most significant aspects of the knowledge of the fast biomass pyrolysis are collected in this chapter, with the objective of analyzing bio-oil production (fast pyrolysis) and its valorization for the production of fuels and raw materials. Attention is focused on the aspects of applied interest for the large-scale implementation of fast pyrolysis by
Jon Alvarez +4 more
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The most significant aspects of the knowledge of the fast biomass pyrolysis are collected in this chapter, with the objective of analyzing bio-oil production (fast pyrolysis) and its valorization for the production of fuels and raw materials. Attention is focused on the aspects of applied interest for the large-scale implementation of fast pyrolysis by
Jon Alvarez +4 more
openaire +1 more source
Toward Understanding of Bio-Oil Aging: Accelerated Aging of Bio-Oil Fractions
ACS Sustainable Chemistry & Engineering, 2014Pyrolysis bio-oil from biomass is a promising intermediate for producing transportation fuels and platform chemicals. However, its instability, often called aging, has been identified as a critical hurdle that prevents bio-oil from being commercialized.
Jiajia Meng +4 more
openaire +1 more source
2015
The fast pyrolysis is a process applied to biomass in order to densifies it, the resulting product is named bio-oil. The bio-oil can serve as a feedstock for the biorefinery. This compound can be transformed into synthesis gas through pyrolysis at higher temperatures.
Costa, L.F.C., Sánchez, C.G.
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The fast pyrolysis is a process applied to biomass in order to densifies it, the resulting product is named bio-oil. The bio-oil can serve as a feedstock for the biorefinery. This compound can be transformed into synthesis gas through pyrolysis at higher temperatures.
Costa, L.F.C., Sánchez, C.G.
openaire +1 more source
Bioresource Technology, 2010
In this study, cattle manure was converted to bio-oil by subcritical hydrothermal liquefaction in the presence of NaOH. The effects of conversion temperature, process gas, initial conversion pressure, residence time and mass ratio of cattle manure to water on the bio-oil yield were studied.
Sudong, Yin +3 more
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In this study, cattle manure was converted to bio-oil by subcritical hydrothermal liquefaction in the presence of NaOH. The effects of conversion temperature, process gas, initial conversion pressure, residence time and mass ratio of cattle manure to water on the bio-oil yield were studied.
Sudong, Yin +3 more
openaire +2 more sources
Bio-oil Production from Biomass: Steps toward Demonstration
Energy & Fuels, 2011Metso, UPM, Fortum, and VTT have developed the worlds first integrated bio-oil production concept to provide an alternative to fossil fuels. The consortium has constructed an up to 7 tons/day bio-oil production pilot unit, which uses a bubbling fluidized-bed (BFB) pyrolysis reactor integrated with a conventional fluidized-bed boiler.
Oasmaa, Anja +9 more
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Catalytic Upgrading of Bio‐Oils by Ketonization
ChemSusChem, 2009Esterrific and ketonderful! Mixtures of acids and esters, produced by esterification reactions with alcohols in bio-oils, can be upgraded to larger ketones by ketonization reactions using a ceria–zirconia catalyst, on which acids adsorb more strongly than esters, leading to the preferential ketonization of acids followed by ketonization of esters at ...
Gärtner, Christian A. +3 more
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