Results 141 to 150 of about 117,195 (298)
Accessing Sn≥2 States of a TADF Emitter by Femtosecond NIR Spectroscopy
The depicted thermally activated delayed fluorescence (TADF) emitter was studied by femtosecond near‐infrared (NIR) spectroscopy. A prominent NIR transition was shown to be strongly solvent‐dependent, with implication for intersystem crossing in the compound.
Wiebke Haselbach +7 more
wiley +1 more source
Synthesis and Reactivity of Extremely Electron‐Poor Au(III) Complexes Bearing OTf− or NTf2− Ligands
A new family of electron‐poor Au(III) cations bearing bistriflimide or triflate ligands is reported. These cations can undergo direct C─H metalation with simple arenes to give mono‐aryl cations. Subsequent addition of simple halide sources allows for reductive elimination of aryl halides, formally from Ar─H and X−. ABSTRACT The synthesis and structural
Lachlan Barwise +6 more
wiley +1 more source
New insights into drug metabolism, distribution, elimination, and detection assays for drugs and methods of sports doping published between 2024 and 2025 are critically reviewed and evaluated in context with the Prohibited List 2025 as established by the World Anti‐Doping Agency.
Mario Thevis, Tiia Kuuranne, Hans Geyer
wiley +1 more source
Fluoro substituents on a benzene ring linked to a 2‐bromoaryl group enables the selective activation of one of its CH bonds via Pd‐1,4‐migration. Then, Pd‐catalyzed direct coupling with heteroarenes produces C2’‐heteroarylated 1,1′‐biaryls. In this reaction, the new C–C bond arises from the functionalization of two CH bonds.
Norman Le Floch +2 more
wiley +1 more source
Synthesis of Sulfur Heterocycles by Palladium‐Catalyzed Cyclization
In spite of the well‐known palladium thiophilicity, sulfur‐containing acyclic substrates may efficiently undergo several different kinds of palladium‐catalyzed cyclization processes leading to highly important sulfur heterocycles in one synthetic step. Advances in this challenging and stimulating field of research are presented in this review.
Bartolo Gabriele
wiley +1 more source
Silyl Rearrangements in Gold‐Catalyzed Transformations
The synergy between the exceptional ability of gold catalysts to activate unsaturated substrates and the inherent tendency of organosilicon reagents to undergo silyl‐group rearrangements has unlocked a range of novel transformations, enabling access to otherwise challenging molecular architectures.
Patricia García‐Martínez +1 more
wiley +1 more source
Biomass‐derived hydrochars as eco‐friendly adsorbents for wastewater treatment applications
Abstract Emerging organic pollutants (EOPs), such as diethyl phthalate (DEP), bisphenol A (BPA), and methylene blue (MB), are only partially removed in conventional wastewater treatment plants. This study assesses hydrochars produced by hydrothermal carbonization (HTC) of spruce bark (SB), vine shoots (VSs), and wheat straw (WSs) for removing three ...
Emanuel Gheorghita Armanu +6 more
wiley +1 more source
From Lipid Regulation to Neuroprotection: Multitarget (Benzo)thiazine Derivatives as Promising Leads. [PDF]
Tzara A, Andreou A, Kourounakis AP.
europepmc +1 more source
Conjugated microporous polymers (CMPs) have attracted more and more attention as new photocatalysts due to their unique advantages such as high performance, long stability and strong light absorption. This review summarizes the application of CMPs as a photocatalyst in recent years and introduces the catalytic mechanism.
Dun Zhou +5 more
wiley +1 more source
Mechanistic profiling and optimized production of Altenusin, a fungal carboxy-biphenyl scaffold for tyrosinase inhibition. [PDF]
Reyes Castillo N +9 more
europepmc +1 more source

