Results 171 to 180 of about 78,578 (289)

Selective Brain-Penetrant TTBK1 Inhibitors Modulate TDP-43 Pathology and Rescue Cognitive Deficits in a Mouse Model of TDP-43 Proteinopathy. [PDF]

open access: yesJ Med Chem
Sanchez-Santos C   +15 more
europepmc   +1 more source

Non‐Covalent Fluorine–Silica Anchoring of a Molecular Platinum(II) bis(NHC) Catalyst: Structure, Interface Control, and Hydrosilylation Activity

open access: yesChemistry – A European Journal, EarlyView.
A Pt(II) bis(NHC) complex is immobilized on mesoporous silica through directional F–Si interactions encoded in the ligand framework. Quantitative 19F{29Si} REDOR experiments and molecular dynamics simulations establish Å‐scale catalyst–support contacts and define the interfacial organization.
Alexander Bergen   +10 more
wiley   +1 more source

Bolapolyphiles With Bulky Carbosilane‐Based Lateral Groups—Reticular Design of Liquid Crystalline Pentagonal Honeycombs

open access: yesChemistry – A European Journal, EarlyView.
T‐shaped bolapolyphiles with highly branched carbosilane‐based side‐groups self‐assemble into liquid crystalline honeycombs composed of type‐2 pentagonal prismatic cells and p2gg plane group symmetry. ABSTRACT Periodic pentagon tessellations are rarely observed in self‐assembled molecular systems.
Christian Anders   +3 more
wiley   +1 more source

<i>N</i>-Phenyl-[1,1'-biphen-yl]-2-carboxamide. [PDF]

open access: yesIUCrdata
Guerah NEH   +4 more
europepmc   +1 more source

Synthesis of Chiral‐at‐Sulfur(VI) Sulfonimidamide Brønsted Acids

open access: yesChemistry – A European Journal, EarlyView.
A simple, modular route to chiral‐at‐sulfur(VI) Brønsted acids is described, delivering S‐chiral sulfonimidamides, C2‐symmetric acids, and BINOL‐based hybrid systems through stereospecific reactions of sulfonimidoyl fluorides and chlorides. ABSTRACT Herein, we report an efficient and simple strategy to access diverse chiral‐at‐sulfur(VI) Brønsted acids.
Yu Han   +6 more
wiley   +1 more source

Chiral Cycloparaarylenes Incorporating Binaphthyl Units: Dramatic Effects of Peripheral Functionalization on (Chir)Optical Properties

open access: yesChemistry – A European Journal, EarlyView.
Chiral cycloparaarylenes (CPAs) incorporating binaphthyl units were synthesized. The methoxy‐substituted and methylenedioxy‐bridged systems adopt D3‐ and C3/C1‐symmetric structures, respectively. They exhibited distinct solid‐state emission and aggregation‐induced emission enhancement (AIEE).
Kazuto Takaishi   +3 more
wiley   +1 more source

Gas–Solid Interface‐Assisted Growth of Organic Semiconductor Single Crystals: Dimensions, Structures, Mechanisms, and Applications

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Gas–solid interface‐assisted growth strategies have unlocked precise control over crystal structure, morphology, dimension, and molecular packing. The obtained organic semiconductor single crystals represent the ideal candidates for high‐performance organic optoelectronic devices.
Tingyi Yan   +8 more
wiley   +1 more source

Synergistic Molecular Engineering and Crosslinking Topology for High‐Temperature Energy Storage in All‐Organic Dielectrics

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
A synergistic strategy combining CF3 group incorporation and crosslinking topology is employed to tailor chain spacing and local ordering in all‐organic dielectrics. This design effectively suppresses carrier migration and enhances polarization, yielding outstanding high‐temperature energy storage performance (e.g., 8.95 J cm−3 with 90% efficiency at ...
Xu Tong   +10 more
wiley   +1 more source

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