Results 121 to 130 of about 3,167,039 (375)

Electrocatalytic Nitrate Reduction to Hydroxylamine: Breaking the Activity‐Selectivity Trade‐Off by Designer Bifunctional Metal‐Organic Frameworks

open access: yesAngewandte Chemie, EarlyView.
A bifunctional metal‐organic framework (MOF) catalyst with dual active sites is developed for enabling NH2OH electrosynthesis via NitRR with both high selectivity and activity. ABSTRACT Electrocatalytic nitrate reduction reaction (NitRR) offers a promising route for hydroxylamine (NH2OH) synthesis under ambient conditions.
Yingying Zou   +9 more
wiley   +2 more sources

Carbons produced from known organic compounds 2. Anthracene-biphenyl and phenanthrene- biphenyl systems [PDF]

open access: yes
Carbonization of binary mixtures of anthracene biphenyl and penanthrene ...
Walker, P. L., Jr., Weintraub, A.
core   +1 more source

Metal phthalocyanine intermediates for the preparation of polymers [PDF]

open access: yes, 1985
Metal 4, 4', 4"",-tetracarboxylic phthalocyanines (MPTC) are prepared by reaction of trimellitic anhydride, a salt or hydroxide of the desired metal (or the metal in powdered form), urea and a catalyst.
Achar, B. N.   +2 more
core   +1 more source

A Generalized Approach for Distal C–H Arylation of Organic Building Blocks: Unveiling the Role of Counter Anion

open access: yesAdvanced Science, EarlyView.
We report a general strategy for meta‐selective C–H arylation using aryl iodides and a Pd(II)/Pd(IV) catalytic system guided by a removable directing group. DFT and experimental studies reveal that counter anion tuning (acetate to trifluoroacetate) significantly enhances selectivity.
Jagrit Grover   +6 more
wiley   +1 more source

Atroposelective Suzuki–Miyaura Coupling to Form 2‐Amino‐2′‐Hydroxybiphenyls Enabled by sRuPhos

open access: yesAngewandte Chemie, EarlyView.
We report a new chiral phosphine ligand, sRuPhos, which permits the highly enantioselective Suzuki–Miyaura coupling of ortho‐aniline and ortho‐phenol building blocks. This results in 2‐amino‐2′‐hydroxybiphenyls with very high enantiomeric excesses, products that will have application in pharmaceutical synthesis and ligand design for catalysis ...
Hamzah Sharif   +3 more
wiley   +2 more sources

Synthesis and optoelectronic properties of new ethynylated pyrazine derivatives [PDF]

open access: yes, 2003
Several diaryleneethynylpyrazine derivatives, in which the pyrazine unit is electron-deficient, have been synthesised using Sonogashira palladium-catalysed cross-coupling reactions.
Zhao, Liang
core  

Observation of Edge‐Confined Acoustic Hyperbolic Polaritons in van der Waals Materials

open access: yesAdvanced Science, EarlyView.
This work demonstrates a new type of light wave—edge‐confined acoustic hyperbolic polaritons—in hexagonal boron nitride on gold. These waves travel along crystal edges with nanoscale confinement and strongly interact with molecular vibrations, enabling highly sensitive detection of tiny molecular layers.
Tianning Zhang   +4 more
wiley   +1 more source

Radical Electroprecipitation from a Water|Oil|Electrode Interface Prolongs “Electro”Chemiluminescence of the Tris(2,2′‐bipyridyl)Ruthenium(II) and Benzoyl Peroxide System by 103

open access: yesAngewandte Chemie, EarlyView.
Multiphase systems, including ones with liquid‐liquid phase boundaries, are the home to many curious chemistries including reaction acceleration and spontaneous formation of reactive species. Here we show the liquid‐liquid interface causes electrochemiluminescence and afterglow chemiluminescence lifetime to be enhanced by 220,000% in‐time, far beyond ...
Daniel M. Carrel   +3 more
wiley   +2 more sources

Record‐High Performance Hyperfluorescent OLEDs Achieved via Electronic Structure Control of Chlorine‐Diversified MR‐TADF Emitters

open access: yesAdvanced Science, EarlyView.
A late‐stage diversification strategy for the benchmark MR‐TADF emitter ω‐DABNA enables precise electronic structure control via chlorine‐activated functionalization. The resulting derivatives achieve tunable emission from 523 to 533 nm with record‐high EQE1000 up to 34.0% and excellent color purity (CIEy = 0.70–0.73), establishing a versatile platform
Taehwan Lee   +7 more
wiley   +1 more source

Home - About - Disclaimer - Privacy