Results 121 to 130 of about 33,101 (301)

Versatile Palladium‐Catalyzed C‐H Arylation of Fluoroarenes with 2‐Chloropyridine Derivatives

Chemistry – A European Journal, EarlyView.
Direct C─H arylation of fluoroarenes with 2‐chloropyridines is enabled by a simple Pd/SPhos system in isopropyl acetate. The method uses inexpensive reactants and shows broad scope and high yields. DFT computations explain reactivity and selectivity.
Federico Belnome, Péter P. Fehér, András Stirling, Csongor G. Németh, Tamás Hergert, György M. Keserű, Péter Ábrányi‐Balogh   +6 more
wiley   +1 more source

Accessing Sn≥2 States of a TADF Emitter by Femtosecond NIR Spectroscopy

Chemistry – A European Journal, EarlyView.
The depicted thermally activated delayed fluorescence (TADF) emitter was studied by femtosecond near‐infrared (NIR) spectroscopy. A prominent NIR transition was shown to be strongly solvent‐dependent, with implication for intersystem crossing in the compound.
Wiebke Haselbach, Jasmin Matthes, Andreas Prüfer, Simon L. Zimmermann, Monika Flörke, Thomas J. J. Müller, Peter Gilch, Barbara E. Nogueira de Faria   +7 more
wiley   +1 more source

Advances in polychlorinated biphenyls degrading bacteria of Burkholderia xenovorans LB400

, 2020
Burkholderia xenovorans LB400 is a strain of polychlorinated biphenyls degrading bacteria PCBs. This organism also cooxidizes chlorinated biphenyl (CB) congeners containing from one to six chlorine substituents.
胡晓珂, 闵军, 李俊德, 孙成成
core  

Biphenyls and their derivatives as synthetically and pharmacologically important aromatic structural moieties

, 2013
Biphenyls are an important intermediate in organic chemistry which constitutes the structural moiety of a wide range of compounds with profound pharmacological activity.
Jain, Zenish J., Gide, Paraag S., Kankate, Rani S.   +2 more
core   +1 more source

Monosubstituted N‐Arylhydroxylamine Chemistry: Integrating Contemporary Synthetic Approaches for the Efficient Construction of Diverse Heterocyclic Scaffolds

Chemistry – A European Journal, EarlyView.
Monosubstituted N‐arylhydroxylamines represent a unique subclass of hydroxylamines that act as pivotal intermediates in redox transformations and as versatile platforms for further synthetic transformations. They serve as key building blocks in the synthesis of architecturally complex heterocycles and other valuable organic compounds.
Michael G. Kallitsakis, Kyriakos D. Nikopoulos, Ioannis N. Lykakis   +2 more
wiley   +1 more source

Kinetics of polychlorinated biphenyls transformation during composting

, 2009
Systematycznie rosnąca ilość wytwarzanych osadów ściekowych w oczyszczalniach stanowi poważny problem ekologiczny. Według danych GUS z 2006r., w Polsce powstaje rocznie około 501,3 tys. ton s.m. osadów ściekowych [6].
Siebielska, I.
core  

Synthesis and Functional Properties of Fluorinated Phosphonate‐Substituted Porphyrins: Excellent Photosensitizers and Robust Precursors for Photoactive Langmuir–Schaefer Films

Chemistry – A European Journal, EarlyView.
This is a comprehensive study of new family of high functionalized meso‐tetraarylporphyrins. A synthetic approach to phosphonate‐substituted fluorinated porphyrins was developed. These compounds were investigated with respect to singlet oxygen generation and photostability.
Azhar Kechiche, Cyrille Monnereau, Chantal Andraud, Alla Bessmertnykh‐Lemeune, Yoann Rousselin, Andrey V. Cheprakov, Elizaveta V. Ermakova, Alexandra I. Zvyagina, Habib Nasri   +8 more
wiley   +1 more source

Highly efficient catalytic hydrodehalogenation of polychlorinated biphenyls (PCBs)

, 2009
The hydrodehalogenation of polychlorinated phenyls and biphenyls (PCBs), catalysed by palladium N-heterocyclic carbene complexes, proceeds with excellent yields, at very low catalyst loadings and at room temperature, using isopropanol as the hydrogen ...
Cazin, Catherine, Cazin, Catherine S. J., Bisaro, Fabrice, Akzinnay, Said   +3 more
core   +1 more source

FLP Mediated Conversion of Difluorobenzylalkynes to Fluoroallenyl Oniums via an SN1’ Pathway

Chemistry – A European Journal, EarlyView.
Frustrated Lewis pair (FLP) selective C‒F activation of difluorobenzylalkynes allows the formation of fluoroallenic oniums via an SN1’ substitution pathway. The fluoroallenic onium salts are synthetic precursors that allow subsequent functionalization at allenic and onium positions.
Max Coles, Tianhong Wang, Rubi McLennan, Long Kit Kwan, Bivas Mondal, Chakyu Richard Chan, Rowan D. Young   +6 more
wiley   +1 more source

Asymmetric Diphosphane Dioxides With A–π–A–π’–D Scaffolds for High‐Purity Deep‐Blue Luminescence

Chemistry – A European Journal, EarlyView.
Diphosphane dioxide‐based luminophores with donor–π–acceptor– π’–acceptor scaffold enable efficient deep‐blue emission from tunable charge‐transfer states affording high photoluminescence up to 95%. OLEDs reach EQE 4.9%, aided by triplet–triplet annihilation, highlighting a practical route to high‐performance blue emitters.
Eetu Hakkarainen, Zong‐Ying Liu, Jhon Sebastian Oviedo Ortiz, Nicolas Vanthuyne, Jeanne Crassous, Ondřej Mrózek, Fabien B. L. Cougnon, Wen‐Yi Hung, Pi‐Tai Chou, Igor O. Koshevoy, Andrey Belyaev   +10 more
wiley   +1 more source