Results 81 to 90 of about 134,326 (323)

Evaluating the Role of the Steroid and Xenobiotic Receptor (SXR/PXR) in PCB-153 Metabolism and Protection against Associated Adverse Effects during Perinatal and Chronic Exposure in Mice. [PDF]

open access: yes, 2020
BACKGROUND:Polychlorinated biphenyls (PCBs) are environmental toxicants; PCB exposure has been associated with adverse effects on wildlife and humans. However, the mechanisms underlying these adverse effects are not fully understood.
Ambrosio, Maria Elena   +6 more
core  

Vacuum‐Evaporated, Lead‐Free RbYbI3 Perovskite Interlayers for Universal Electron Injection in High‐Performance Organic Light‐Emitting Diodes

open access: yesAdvanced Materials, EarlyView.
ABSTRACT The optoelectronic performance of organic light‐emitting diodes (OLEDs) is critically governed by charge injection from electrodes into organic layers, where significant energy barriers at the interfaces often impede efficient charge injection.
Amarja S. Katware   +7 more
wiley   +1 more source

Persistent organic pollutants and cognitive decline among middle-aged or older adults in the Hispanic Community Health Study/Study of Latinos

open access: yesEcotoxicology and Environmental Safety
Persistent organic pollutants may negatively impact cognition; however, associations between persistent organic pollutants and changes in cognition among United States Hispanic/Latino adults have not been investigated.
Humberto Parada, Jr   +8 more
doaj   +1 more source

Hybridized Charge‐Transfer Window within a Fully Conjugated Multi‐Resonance Thermally Activated Delayed Fluorescence Framework for Ultrafast Reverse Intersystem Crossing and High‐Efficiency in Deep‐Blue Organic Light‐Emitting Diodes

open access: yesAdvanced Materials, EarlyView.
A hybridized charge‐transfer window combining short‐range and long‐range charge transfer is realized within a fully conjugated multi‐resonance thermally activated delayed fluorescence framework. The resulting excited‐state hybridization minimizes the singlet–triplet energy gap (0.04 eV) and enables ultrafast reverse intersystem crossing (krISC = 2.1 ...
Uisung Lee   +3 more
wiley   +1 more source

Bay‐functionalized [7]Helicene Bilayer Nanographenes

open access: yesAdvanced Optical Materials, EarlyView.
Bay‐functionalized [7]helical bilayer nanographenes are synthesized via a scalable, modular strategy enabling late‐stage diversification. Tailored methoxy, diketone, and phenazine substitutions precisely tune redox, photophysical, and chiroptical properties, delivering strong electronic circular dichroism and bright circularly polarized luminescence ...
Anmol Thanai   +9 more
wiley   +1 more source

An Organometallic [2]Catenane With Pt‒(di‐NHC)‒Pt Units: A Topology‐Driven Strategy for Enhanced Phosphorescence in Discrete Aggregates

open access: yesAngewandte Chemie, EarlyView.
The mechanically interlocked Borromean rings are stabilized by π···π stacking interactions while the [2]catenane is stabilized by solvophobic effects. While the π···π interactions in the Borromean rings lead to severe luminescence quenching, the solvophobically assembled [2]catenane effectively circumvents these interactions, simultaneously restricting
Ye Lu   +5 more
wiley   +2 more sources

Helix Alignment, Chevrons, and Edge Dislocations in Twist‐Bend Ferroelectric Nematics

open access: yesAdvanced Science, EarlyView.
The recently discovered twist‐bend ferroelectric nematic (NTBF) is the new member of the multiferroic family, representing a fluid with an oblique helicoidal (heliconical) periodic structure of spontaneous electric polarization. The work presents a thorough exploration of the material properties of this phase, how the periodic modulation of ...
Bijaya Basnet   +8 more
wiley   +1 more source

Biomonitoring of the genotoxic potential of aqueous extracts of soils and bottom ash resulting from municipal solid waste incineration, using the comet and micronucleus tests on amphibian (Xenopus laevis) larvae and bacterial assays (MutatoxR and Ames tests) [PDF]

open access: yes, 2006
The management of contaminated soils and wastes is a matter of considerable human concern. The present study evaluates the genotoxic potential of aqueous extracts of two soils (leachates) and of bottom ash resulting from municipal solid waste ...
Devaux, Alain   +6 more
core   +2 more sources

Climate Action Impacts on Steelmaking Emissions of Persistent Organic Pollutants Highlight a Gap Between the Paris Agreement and the Stockholm Convention

open access: yesAdvanced Science, EarlyView.
Emissions of unintentionally produced persistent organic pollutants (UPOPs) and global warming are two major environmental challenges. But their governance has largely evolved in parallel, leaving the toxicity implications of climate‐driven industrial transitions poorly understood.
Yuxiang Sun   +7 more
wiley   +1 more source

Aryl and Alkyl Radiotrifluoromethylation via Metallaphotoredox‐Mediated Radical Cross‐Coupling

open access: yesAngewandte Chemie, EarlyView.
The metallaphotoredox‐mediated radiotrifluoromethylation of arenes and alkanes is described. The operationally simple protocols make use of substrates bearing thianthrenium salts (TT) or N‐hydroxyphthalimide (NHPI) esters and CF218FI. The reaction proceeds through a Ru‐mediated radical formation followed by a Cu‐mediated radical cross‐coupling step and
Lukas Veth   +2 more
wiley   +2 more sources

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