Removal of Cu(II) and Ni(II) Metal Ions from Aqueous Solutions Using Modified Hydroxyapatite by Zero-Valent Iron Nanoparticles [PDF]
In this study, hydroxyapatite-supported zero-valent iron nanoparticle was synthesized by the sodium borohydride reduction method. To evaluate the performance of adsorbent for the removal of Cu(II) and Ni(II) ions, the influence of different sorption ...
Mohammad Javad Amiri
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Controlled Synthesis of Silver Nanoparticles Using Double Reductants and Its Voltammetric Characteristics Study [PDF]
Constructing robust silver nanoparticles (AgNPs) with good shape and dispersibility is of particular interest in analytical applications. Herein, monodispersibility AgNPs with the average size of 20 nm have been successfully prepared via one-pot method ...
Duan, Yubo, Jiang, Xiaochun, Xu, Zhihua
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REACTIVITY OF CHLOROPHYLL a/b-PROTEINS AND MICELLAR TRITON X-100 COMPLEXES OF CHLOROPHYLLS a OR b WITH BOROHYDRIDE [PDF]
The reaction of several plant chlorophyll-protein complexes with NaBH4 has been studied by absorption spectroscopy. In all the complexes studied, chlorophyll b is more reactive than Chi a, due to preferential reaction of its formyl substituent at C-7 ...
Arnon D. I. +15 more
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Abstract In this study, a novel desulfurization method was developed by introducing ionic liquid (IL) into the integrated process of reductive desulfurization by NaBH4 and its regeneration via NaBO2 electroreduction, where ILs play a dual role of electrolyte and extracting agent.
Chenhua Shu +6 more
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The present work reported a novel strategy to construct supported cationic-polystyrene-resin-bound silver nanocomposites for enhanced catalytic reduction of 4-nitrophenol in an aqueous medium.
Anushree Saha +3 more
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CHEMICALLY MODIFIED PHOTOSYNTHETIC BACTERIAL REACTION CENTERS: CIRCULAR DICHROISM, RAMAN RESONANCE, LOW TEMPERATURE ABSORPTION, FLUORESCENCE AND ODMR SPECTRA AND POLYPEPTIDE COMPOSITION OF BOROHYDRIDE TREATED REACTION CENTERS FROM Rhodobacter sphaeroides R26 [PDF]
Reaction centers from Rhodobacter sphaeroides have been modified by treatment with sodium borohydride similar to the original procedure [Ditson et al., Biochim. Biophys. Acta 766, 623 (1984)], and investigated spectroscopically and by gel electrophoresis.
Angerhofer A. +14 more
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Chemical Synthesis and Characterization of Pd/SiO2: The Effect of Chemical Reagent
The size and shape distribution of metal nanoparticles (NPs) are important parameters that need to be tuned in order to achieve desired properties of materials for practical applications.
Aram L. Bugaev +8 more
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Synthesis and properties of nickel-cobalt-boron nanoparticles [PDF]
morphous cobalt nickel boride nanoparticles were synthesised by chemical reduction synthesis in aqueous solution. Careful control of synthesis conditions and post reaction oxidation enabled the nanoparticles to be converted into a core-shell structure ...
Pankhurst, QA, Parkin, IP, Patel, J
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PtRu/C (50:50) and PtRuBi/C (50:40:10) electrocatalysts were prepared by borohydride reduction using H2PtCl6.6H2O, RuCl3.xH2O and Bi(NO3)3.5H2O as metals sources and Vulcan XC72 as support.
Michele Brandalise +5 more
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Elucidating Dramatic Ligand Effects on SET Processes: Iron Hydride versus Iron Borohydride Catalyzed Reductive Radical Cyclization of Unsaturated Organic Halides [PDF]
An iron(II) borohydride complex ([(η1-H3BH)FeCl(NCCH3)4]) is employed as the precatalyst in iron-catalyzed radical cyclizations of unsaturated organic halides in the presence of NaBH4. Mechanistic investigations have established that the ligand bound to the metal center (acetonitrile versus ethylenebis(diphenylphosphine) (dppe)) plays a crucial role in
Kyne, Sara +7 more
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