Results 91 to 100 of about 15,382 (260)

Heterovalent, Homometallic Rings: Synthesis, Optical, and EPR Studies of {TiIV7TiIII} Complexes

Chemistry – A European Journal, EarlyView.
A new class of heterovalent, homometallic complexes is reported, based on cyclic {TiIV7TiIII} cores with oxide and carboxylate bridges between nearest neighbors. The clusters show Class II mixed‐valent behavior at room temperature, but are valence localized at low temperature.
Selena J. Lockyer, Lubomir Loci, Yingzhao Ma, Matthew P. Stevens, Grigore A. Timco, George F. S. Whitehead, Richard E. P. Winpenny, Alice M. Bowen, Eric J. L. McInnes   +8 more
wiley   +1 more source

Linker Symmetry Lowering as a Strategy to Tune Electronic Properties in Two‐Dimensional Conductive MOFs

Chemistry – A European Journal, EarlyView.
We present a two‐dimensional conductive metal‐organic framework (2D cMOF) constructed from an organic linker with lower symmetry than those commonly used in related systems. The resulting reduction in lattice symmetry lifts band degeneracies, reshapes the electronic structure, and opens a larger band gap.
Bowen Tan, Tianyang Chen, Mingyu Jeon, Julius J. Oppenheim, Mircea Dincă   +4 more
wiley   +1 more source

Firm‐Level Corporate Social Responsibility and Employees' Affective Outcomes: A Multilevel Approach

Corporate Social Responsibility and Environmental Management, EarlyView.
ABSTRACT This study advances research on corporate social responsibility (CSR) and employees' work attitudes by distinguishing between employee‐level CSR perceptions and firm‐level CSR practices. Prior research has mainly focused on how employees' perceptions of CSR relate to their affective outcomes; this study extends that perspective by jointly ...
Alexander C. Kraaij, Agnieszka Paruzel, Arnoud de Jong   +2 more
wiley   +1 more source

A Multilevel Framework of Employee Environmental Initiatives: The Role of Departmental Climate, Departmental Management's Green Leadership, and Corporate Environmental Responsibility

Corporate Social Responsibility and Environmental Management, EarlyView.
ABSTRACT This study develops a multilevel framework to examine how employees' discretionary environmental initiatives are shaped by organizational and departmental contexts. Using survey data from 150 employees across 25 organizations, we integrate organizational climate and leadership theories to investigate the effects of Corporate Environmental ...
Yousef Eiadat
wiley   +1 more source

Fracture evolution of a thick soft protection layer and the water inrush mechanism in overburden under longwall mining

Deep Underground Science and Engineering, EarlyView.
Through shear–tensile creep tests and viscoelastic modeling, the fracture evolution of thick soft protective layers is clarified. Results show thickness‐dependent rheological failure modes that govern four types of roof water inrush, providing a mechanism‐based framework for hazard prediction and control. Abstract In the Jurassic coal‐bearing strata of
Mengnan Liu, Wei Qiao, Xianggang Cheng, Xiangsheng Meng, Peichao Feng   +4 more
wiley   +1 more source

Community‐level egg and larval trait interactions with the Amazon River plume determine its role as a dispersal barrier

Ecography, EarlyView.
The Amazon River plume (ARP) functions as a dynamic and porous biogeographic barrier whose permeability to larval dispersal depends on the interplay between species' biological traits and oceanographic processes. Using biophysical modeling combined with a dual analytical framework, namely a multivariate regression tree (MRT) and a generalized additive ...
Ramon B. Santos, Nelson A. Gouveia, Douglas F. M. Gherardi   +2 more
wiley   +1 more source

Light‐Driven Butyrate Production by a Probiotic Clostridium tyrobutyricum Enabled by a Cell‐Semiconductor Hybrid Interface

Food Chemistry International, EarlyView.
This schematic illustrates a light‐driven biohybrid system where CdS nanoparticles, mineralized on the probiotic Clostridium tyrobutyricum, inject photoelectrons to elevate intracellular NADH. This boosts the flux through key NADH‐dependent enzymes (GapA, Hbd, and Bcd), reprogramming metabolism to enhance butyrate yield by 33.2% and selectivity to 95.7%
Qianru Zhao, Zhihan Yang, Bowen Shen, Ling Jiang   +3 more
wiley   +1 more source

Lycopene‐rich food biomolecules from tomato processing waste: Green recovery, biopolymer‐based stabilisation, functional food applications and health relevance

Food Biomacromolecules, EarlyView.
Abstract Tomato processing waste, particularly peel and pomace, is a sustainable and low‐cost source of lycopene‐rich food biomolecules. Lycopene, a lipophilic carotenoid with an extended conjugated structure, provides intense red colour, antioxidant potential and functional value to tomato‐derived ingredients.
Chandan Kumar Sahu, Mrinmoy Roy
wiley   +1 more source

Local Structures of Se and Br in Cretaceous–Paleogene Boundary Sediments and Concentration Effects of Ferrihydrite Originating From Impact Ejecta

Geological Journal, EarlyView.
Chemical states of Se and Br atoms in the KPg boundary sediments from Stevns Klint were studied using XAFS spectroscopy. The high concentrations of Se4+ could become an index of the degree to which the global environment was soiled with dust and ash derived from impact ejecta or volcanic eruptions.
Kei‐ichiro Murai, Akira Yoshiasa, Ginga Kitahara, Makoto Tokuda, Satoko Ishimaru, Toshihiro Moriga   +5 more
wiley   +1 more source

Green swans and blue skies: Climate change and insolvency risk for financial institutions

International Insolvency Review, EarlyView.
Abstract This lecture in honour of the late Gabriel Moss QC and Ian Fletcher QC examines the challenge of climate‐related financial risk. Prudential regulators and central banks recognize that the systemic nature of climate‐related financial risk makes it an emerging vulnerability relevant to cross‐border insolvency resolution.
Janis Sarra
wiley   +1 more source