Results 161 to 170 of about 41,581 (262)

Decoupling Activation and Preservation: Architectural Design Principles of Organic Frameworks for Selective Photocatalytic Methane Oxidation

open access: yesAdvanced Materials, EarlyView.
Selective methane (CH4) photooxidation emerges from architectural decoupling of activation and preservation. Programmable organic semiconductor frameworks spatially organize oxidative flux and intermediate residence, separating reaction zones from product domains to synchronize activation strength with stabilization and establish a selective oxidation ...
Minxian Zhang   +5 more
wiley   +1 more source

Can Elastomers Combine Stiffness, Toughness and Fatigue Resistance?

open access: yesAdvanced Materials, EarlyView.
This review studies how the molecular and macroscopic architecture of elastomers influence their mechanical properties including: stiffness, stretchability, toughness, fatigue resistance, and damping behavior. By linking the structure to performance, it proposes design principles for advanced elastomeric systems that combine mechanical properties ...
Eva Baur, Esther Amstad
wiley   +1 more source

Far‐Infrared Hyperbolic Phonon–Polaritons in Zirconium Disulfide

open access: yesAdvanced Materials, EarlyView.
An unpatterned ZrS2${\rm ZrS}_2$ flake, coupled to far‐field infrared light by metal nanoribbons, reveals hyperbolic phonon polaritons with multiple higher‐order branches and effective refractive indices up to 223. This resonator‐assisted approach establishes ZrS2${\rm ZrS}_2$ as a compact van der Waals platform for deeply subwavelength far‐infrared ...
Subhodip Saha   +7 more
wiley   +1 more source

Unveiling α‐MoO3 as a High‐Index, Low‐Loss Anisotropic Material: Bridging the Gap From Mid‐Infrared to Ultraviolet Nanophotonics

open access: yesAdvanced Materials, EarlyView.
α‐MoO3 is established as a high‐index, low‐loss anisotropic platform bridging mid‐infrared polaritonics and ultraviolet‐visible nanophotonics. Spectroscopic ellipsometry and calculations reveal refractive indices exceeding 3.9, with the largest in‐plane birefringence among transparent layered crystals at 425–500 nm, enabling zero‐order UV waveplates ...
Adilet N. Toksumakov   +14 more
wiley   +1 more source

True Closed‐Loop Recyclable Hydrogels Enabled by Imine Boronic Ester Crosslinking

open access: yesAdvanced Materials, EarlyView.
Subtle molecular differences in imine boronic ester crosslinkers profoundly influence hydrogel properties. 2‐formylphenylboronic acid crosslinkers form previously undisclosed 3‐amino‐benzoxaborole heterocycles, enhancing elasticity despite lower crosslinking density compared to their 4‐formylphenylboronic acid counterparts.
Jenna A. King   +5 more
wiley   +1 more source

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