Chirality induction by E-Z photoisomerization in [2,2]paracyclophane-bridged azobenzene dimer
Chirality induction by E-Z photoisomerization in [2,2]paracyclophane-bridged azobenzene dimerWe designed and synthesized a new prochiral molecule in which two azobenzene moieties were embedded in [2,2]paracyclophane and showed the chirality induction by E-Z photoisomerization. We also demonstrated the on/off switching of asymmetry by irradiation and reflux respectively.
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