Results 131 to 140 of about 78,896 (178)

Photochemical dynamics simulations for trans–cis photoisomerizations of azobenzene and bridged azobenzene

open access: yesComputational and Theoretical Chemistry, 2014
Surface hopping dynamics simulations based on the Zhu-Nakamura theory were performed to investigate the trans-cis photoisomerization mechanisms of azobenzene and bridged azobenzene excited to S-1 state. In geometry optimization, both for the two compounds, two minimum-energy conical intersections between the ground state and the lowest excited state ...
Peiyu Zhang, Bin Li, Jian-Yong Liu
exaly   +3 more sources

Light-induced healing in azobenzene bridged silsesquioxanes

open access: yesEuropean Polymer Journal, 2019
Abstract Intrinsic healable polymers are materials capable of repairing itself through its chemical nature, in order to improve stability and durability and to restore the lost functionalities or properties. In this study, azobenzene (AZO) moieties were incorporated into a previously reported bridged silsesquioxane based on the reaction of ...
Patricia Oyanguren   +2 more
exaly   +4 more sources

Photo-Induced Switchable Binding Behavior of Bridged Bis(β-cyclodextrin) with an Azobenzene Dicarboxylate Linker [PDF]

open access: yesJournal of Inclusion Phenomena and Macrocyclic Chemistry, 2006
A bridged bis(β-cyclodextrin) (1) with an azobenzene dicarboxylate linker was synthesized, and its binding behavior with a fluorescent dye, acridine red (AR), was investigated by means of fluorescence spectroscopy. Due to the photo-induced conversion of the azobenzene dicarboxylate linker from the trans-conformer to the cis-conformer, 1 exhibits a ...
Ying-Wei Yang   +2 more
exaly   +4 more sources

Azobenzene-Bridged Expanded “Texas-sized” Box: A Dual-Responsive Receptor for Aryl Dianion Encapsulation

open access: yesJournal of the American Chemical Society, 2019
We report an expanded "Texas-sized" molecular box (AzoTxSB) that incorporates photoresponsive azobenzene bridging subunits and anion recognition motifs. The shape of this box can be switched through light induced E ↔ Z photoisomerization of the constituent azobenzenes.
Wanglai Cen   +2 more
exaly   +7 more sources

Excited State Charge Separation in an Azobenzene-Bridged Perylenediimide Dimer – Effect of Photochemical Trans-Cis Isomerization [PDF]

open access: yesChemistry - A European Journal, 2021
Article demonstrating photoinduced charge transfer and separation events in a newly synthesized azobenzene-bridged perylenediimide-dimer (PDI-dimer). Results offer key insights on the role of the azobenzene bridge and the dimer geometry in governing the ...
David Gutiérrez-Moreno   +2 more
exaly   +2 more sources
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Azobenzene-bridged calix[8]arenes

Tetrahedron Letters, 2006
An azobenzene bridge was introduced into the lower (or smaller) rim of p-tert-butylcalix[8]arene (1) and 1,5-calix[8]crown-3 (2) to form 1,4-singly bridged (3) and 1,5:3,7-doubly bridged (4) calix[8]arene derivatives, respectively. Trans and cis isomers of conformationally rigid 4 were isolated.
Corrada Geraci   +2 more
exaly   +5 more sources

Unraveling a Chemically Enhanced Photoswitch: Bridged Azobenzene†

Angewandte Chemie - International Edition, 2010
Nikos L Doltsinis   +2 more
exaly   +4 more sources

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