Enantioselective Synthesis of Bridged Bicyclic Ring Systems
The type 2 intramolecular Diels−Alder (IMDA) reaction is a valuable method for synthesis of both carbocyclic and heterocyclic bridged bicyclo[5.3.1]undecane and bicyclo[4.3.1]decane ring systems.
Liang Zhu (172992) +3 more
core +1 more source
Rhodium(I)-Catalyzed Annulation of Bicyclo[1.1.0]butyl-Substituted Dihydroquinolines and Dihydropyridines [PDF]
Bicyclo[1.1.0]butane-containing compounds feature a unique chemical reactivity, trigger “strain-release” reaction cascades, and provide novel scaffolds with considerable utility in the drug discovery field.
Wipf, Peter +5 more
core +1 more source
Designing and looking for novel cage compounds based on bicyclo-HMX as high energy density compounds
We designed four cage compounds by introducing intramolecular linkages into the bicyclo-HMX framework. Their molecular and electronic structures, energetic properties, thermal stability, and impact sensitivity were evaluated using DFT.
Yong Pan, Weihua Zhu
core +1 more source
Novel Liquid Crystalline Compounds Containing Bicyclo[3.1.0]hexane Core Units
Additions of ethyl or tert-butyl diazoacetates to 4-substituted cyclopentenes 6 and 17 under dirhodium tetraacetate/tetraoctanoate catalysis led to mixtures of tert-butyl endo,exo and exo,exo-3-carboxyl(aryl)bicyclo[3.1.0]hexane-6-carboxylates 7 and 18 ...
Armin de Meijere +15 more
core +1 more source
Accessing Medium-Sized Bridged Heterocycles via EnT-Catalyzed Intermolecular Dearomative (5 + 4) Cycloaddition of Furans and Oxazoles. [PDF]
Hümpel C +5 more
europepmc +1 more source
How Spin Conductive are Oligo(p-phenylenes) in Trityl-Based Biradicals. [PDF]
Kopp KL +3 more
europepmc +1 more source
Annulation of Hydroxyarenes and Derivatives with Bicyclo[1.1.0]butanes by Synergistic Combination of Metal Lewis Acid and Organic Acid. [PDF]
Guo Q, Ni D, Deng L.
europepmc +1 more source
Complete Computational Exploration of Eight-Carbon Hydrocarbon Chemical Space. [PDF]
Harman SJ, Ermanis K.
europepmc +1 more source
Lewis Acid-Catalyzed Divergent (4+3)/(4+2) Annulations of o-Quinone Methides with Bicyclo[1.1.0]butanes Lead to sp3-Rich Oxabicyclic Frameworks. [PDF]
Mondal S +4 more
europepmc +1 more source

