Valence and spin states of iron are invisible in Earth’s lower mantle
Bridgmanite is the most abundant mineral in the lower mantle and therefore is crucial to interpreting geophysical observations and models. Here, the authors show that ferric-iron-only bridgmanite Fe3+ undergoes a spin transition at 43–53 GPa at 300 K and
Jiachao Liu +8 more
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Formation of large low shear velocity provinces through the decomposition of oxidized mantle
Dense Fe3+-rich bridgmanite can explain the seismic features of Large Low Shear Velocity Provinces, as it can form large-scale thermochemical piles in the deep mantle that remain stable throughout Earth’s history.
Wenzhong Wang +6 more
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Mantle dynamics inferred from the crystallographic preferred orientation of bridgmanite [PDF]
Seismic shear wave anisotropy is observed in Earth's uppermost lower mantle around several subducted slabs. The anisotropy caused by the deformation-induced crystallographic preferred orientation (CPO) of bridgmanite (perovskite-structured (Mg,Fe)SiO3) is the most plausible explanation for these seismic observations. However, the rheological properties
Tsujino, Noriyoshi +5 more
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Natural Fe-bearing aluminous bridgmanite in the Katol L6 chondrite
Significance Bridgmanite is the most volumetrically abundant mineral of the Earth’s interior, and it is important to understand its formation mechanism to better comprehend the origin and evolution of planetary interiors.
Sujoy Ghosh +7 more
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Oxygen Vacancy Substitution Linked to Ferric Iron in Bridgmanite at 27 GPa [PDF]
AbstractFerric iron can be incorporated into the crystal structure of bridgmanite by either oxygen vacancy substitution (MgFeO2.5 component) or charge‐coupled substitution (FeFeO3 component) mechanisms. We investigated the concentrations of MgFeO2.5 and FeFeO3 in bridgmanite in the MgO‐SiO2‐Fe2O3 system at 27 GPa and 1700–2300 K using a multianvil ...
Fei, Hongzhan +3 more
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Melting phase relations in the MgSiO3–CaSiO3 system at 24 GPa
The Earth’s lower mantle is composed of bridgmanite, ferropericlase, and CaSiO3-rich perovskite. The melting phase relations between each component are key to understanding the melting of the Earth’s lower mantle and the crystallization of the deep magma
Ryuichi Nomura +2 more
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Shear deformation of bridgmanite and magnesiowüstite aggregates at lower mantle conditions [PDF]
Mantle minerals won't share the strain The deformation of a mixed block of material depends on the strength of the components of which it is made. Weak materials will deform more than the strong ones in a mixture that is squished or stretched. Girard et al.
Jennifer, Girard +4 more
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Iron partitioning between ferropericlase and bridgmanite in the Earth's lower mantle [PDF]
AbstractEarth's lower mantle is generally believed to be seismically and chemically homogeneous because most of the key seismic parameters can be explained using a simplified mineralogical model at expected pressure‐temperature conditions. However, recent high‐resolution tomographic images have revealed seismic and chemical stratification in the middle‐
Shenzhen Xu, Jung‐Fu Lin, Dane Morgan
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Aluminum Components in Bridgmanite Coexisting With Corundum and the CF‐Phase With Temperature
AbstractPhase relations in the MgSiO3–MgAl2O4–Al2O3 system are investigated at 27 GPa and 2000–2600 K using a multi‐anvil apparatus. The AlAlO3 content in the bridgmanite increases from 8.6 to 20.0 mol% with increasing temperature from 2000 to 2600 K, while the MgAlO2.5 content remains nearly constant, that is, 3–4 mol% at these temperatures. Therefore,
Wang, Lin +8 more
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Density functional theory calculations and thermodynamic analysis of bridgmanite surface structure [PDF]
Bridgmanite surface structure variations as a function of chemical potentials of Mg and O at the upper most of the Earth's lower mantle condition (∼660 km).
Ming Geng, Hannes Jónsson
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