Results 41 to 50 of about 24,449 (196)

Single‐Crystal Organic Field‐Effect Transistors Based on 5,15‐Bisaryl‐Tetrabenzoporphyrins: Synthesis, Structure, and Charge Transport Properties

Advanced Materials Interfaces, EarlyView.
This study explores single‐crystal organic field‐effect transistors (SC‐OFETs) based on 5,15‐bisaryl‐tetrabenzoporphyrin derivatives. It highlights the impact of meso‐substituted groups on molecular packing and charge transport. Among the derivatives, C8Ph‐BP achieves the highest hole mobility (1.64 cm2 V−¹ s−¹) due to enhanced π‐stacking with ...
Kazuya Miyazaki, Kento Teranishi, Hiroshi Matsuda, Kyohei Matsuo, Mitsuaki Yamauchi, Yoshiyuki Mizuhata, Nobutaka Shioya, Takeshi Hasegawa, Hiroko Yamada   +8 more
wiley   +1 more source

Self‐Supporting Graphene Foam for the Removal of Chlorine from Water

Advanced Materials Interfaces, EarlyView.
Graphene‐based porous materials are promising for sorption and catalysis but often require binders. This study presents a self‐supporting graphene foam made from graphene oxide and hydrazine vapor. Structural, mechanical, and functional analyses confirm its superior chlorine removal efficiency (97%) and reusability, outperforming activated carbon in ...
Konrad Dybowski, Grzegorz Romaniak, Bartłomiej Januszewicz, Anna Sobczyk‐Guzenda, Jacek Grabarczyk, Adam Puszkarz, Anna Jędrzejczak   +6 more
wiley   +1 more source

PTC in the Polyenolate‐Mediated [10+2]‐Cycloaddition for the Synthesis of α,α‐Disubstituted Amino Acid Precursors

Advanced Synthesis &Catalysis, EarlyView.
Abstract The manuscript describes a formal [10+2] higher‐order cycloaddition between 2‐arylideneindan‐1‐ones and α‐alkylidene azlactones as higherene precursors and higherenofiles respectively. The reaction is realized under Brønsted‐base catalysis utilizing the phase transfer catalysis approach.
Joanna Dybowska, Artur Przydacz, Anna Skrzyńska, Łukasz Albrecht   +3 more
wiley   +1 more source

Heterogeneously Catalyzed Cascade Oxidative Coupling/Dearomative Spirocyclization of Diarylamines: Facile Access to Spiroacridines

Advanced Synthesis &Catalysis, EarlyView.
Abstract Spirocyclic compounds, particularly spirocyclohexadienones, are important in pharmaceuticals due to their biological activity. In this study, we develop a catalytic cascade oxidative spirocyclization of diarylamines for the rapid access to highly functionalized spirocyclohexadienones. Using commercially available recyclable heterogeneous metal
Kenji Matsumoto, Naho Sato, Yoshinori Kobayashi, Kanako Date, Yasuko Okamoto, Touya Kariya, Tsukasa Hirokane, Masahiro Yoshida   +7 more
wiley   +1 more source

Development of Photo‐Biocatalytic Redox System for Asymmetric Synthesis of Optically Active Amines Using Blue Light and Transaminases. A Case Study Toward Mavacamten

Advanced Synthesis &Catalysis, EarlyView.
Abstract α‐Chiral amines are versatile building blocks for the asymmetric synthesis of optically pure high‐added‐value chemicals, including pharmaceuticals, agrochemicals, and natural products. Herein, we report a one‐pot, two‐step sequential deracemization of racemic sec‐alcohols to optically enriched primary amines throught a photo‐biocatalytic ...
Natalia Antos, Aleksandra Rudzka, Anna Hoser, Tamara Reiter, Wolfgang Kroutil, Paweł Borowiecki   +5 more
wiley   +1 more source

Modular Synthesis of 2,3,4,6‐Tetrasubstituted Thieno[2,3‐c]furans Based on Formal [3+2] Cycloaddition Utilizing [1,2]‐Phospha‐Brook Rearrangement / Brønsted Base‐Mediated Cyclization Strategy

Advanced Synthesis &Catalysis, EarlyView.
Abstract A modular synthesis of 2,3,4,6‐tetrasubstituted thieno[2,3‐c]furans, which employs a formal [3+2] cycloaddition utilizing the [1,2]‐phospha‐Brook rearrangement and a subsequent Brønsted base‐mediated cyclization, has been established, providing an efficient access to a wide range of densely functionalized thieno[2,3‐c]furans that are otherwise
Azusa Kondoh, Kohei Aita, Masahiro Terada   +2 more
wiley   +1 more source

Innovative Integration of Layered Carbon Materials in Biopolymer Fibrous Membranes for Sustainable Water Treatment

Advanced Sustainable Systems, EarlyView.
This review explores the progressive design of biopolymer‐based fibrous membranes enhanced with layered carbon materials such as MXene, graphene oxide, and carbon nanotubes. It highlights how their integration significantly boosts water filtration performance, selectivity, and antifouling properties.
Sanaz Khademolqorani, Kinjal J Shah, Mandana Dilamian, Ahmed I. Osman, Esra Altiok, Shohreh Azizi, Ilunga Kamika, Yuxin Yang, Fatma Yalcinkaya, Andre Yvaz, Seyedeh Nooshin Banitaba   +10 more
wiley   +1 more source

Shrimp Virus Regulates ROS Dynamics via the Nrf2 Pathway to Facilitate Viral Replication

Advanced Science, EarlyView.
Viruses manipulate host ROS as a strategy to achieve successful infection. WSSV exploits Nrf2 pathway to maintain ROS homeostasis and establishes a positive feedback loop to facilitate WSSV replication. Wsv220 competitively binds to Keap1 to activate Nrf2. Nrf2 up‐regulates LvG6PDH to produce more NADPH and GSH to eliminate excessive ROS.
Honghui He, Kai Yuan, Junming Pan, Shaoping Weng, Chaozheng Li, Yihong Chen, Jianguo He   +6 more
wiley   +1 more source

Advancements in Biochar as a Sustainable Adsorbent for Water Pollution Mitigation

Advanced Science, EarlyView.
Biochar, obtained through pyrolysis of organic waste, serves as a sustainable solution for wastewater treatment due to its adaptability and low‐cost nature. This review comprehensively examines recent advancements in biochar production, functional modifications, and applications, highlighting the integration of machine learning and artificial ...
Devika Laishram, Su‐Bin Kim, Seul‐Yi Lee, Soo‐Jin Park   +3 more
wiley   +1 more source

Hydrogen Drives Part of the Reverse Krebs Cycle under Metal or Meteorite Catalysis

Angewandte Chemie International Edition, Volume 61, Issue 51, December 19, 2022., 2022
Hydrogen is a geological reducing agent that powers the metabolisms of modern organisms and potentially also powered the metabolism of the last universal common ancestor to all extant life. It is shown that catalytic amounts of transition metals or small amounts of powdered meteorites allow hydrogen to drive a key sequence of the reverse Krebs cycle ...
Sophia A. Rauscher, Joseph Moran
wiley   +1 more source