Results 171 to 180 of about 2,664 (258)

π‐Extended Silyl Enolates as Emerging Platforms in Radical Chemistry

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
This review covers the emerging role of π‐extended silyl polyenol ethers in radical chemistry. It highlights their versatile roles as electron‐rich SOMOphiles, silyl radical cation precursors, and nucleophilic partners in radical–polar crossover manifolds, while considering recent advances in photoredox catalysis, electrochemistry, and transition metal‐
Debora Guazzetti   +3 more
wiley   +1 more source

Inconsistent Transcriptomic Responses to Hexabromocyclododecane in Japanese Quail: A Comparative Analysis of Results From Four Different Study Designs

open access: yesEnvironmental Toxicology and Chemistry, EarlyView.
Abstract Efforts to use transcriptomics for toxicity testing have classically relied on the assumption that chemicals consistently produce characteristic transcriptomic signatures that are reflective of their mechanism of action. However, the degree to which transcriptomic responses are conserved across different test methodologies has seldom been ...
Paul Béziers   +10 more
wiley   +1 more source

Heteroatom location‐ and orientation mode‐dependent reverse intersystem crossing rate in multiple resonance emitters

open access: yesFlexMat, EarlyView.
By constructing two pairs of isomers with different heteroatom anchoring positions, the relationship between heteroatom location and orientation mode and reverse intersystem crossing rate constant (kRISC) in multiple resonance (MR) emitters is systematically investigated.
Tingting Huang   +5 more
wiley   +1 more source

The role of additives in the film formation kinetics of active layers in organic solar cells: From in situ characterization to mechanistic elucidation

open access: yesFlexMat, EarlyView.
This review highlights the critical regulatory role of liquid and solid additives in the film formation kinetics of organic solar cells (OSCs) active layer. Real‐time in situ characterization technology techniques (in situ UV‐Vis, PL, GIWAXS, and GISAXS) are utilized to monitor the dynamic solution‐to‐solid transformation, revealing how additives ...
Yuanwei Zhao   +8 more
wiley   +1 more source

Research progress in photo‐controlled radical involved luminescence materials

open access: yesFlexMat, EarlyView.
This review systematically dissects radical generation mechanisms, triplet‐exciton photophysics, material design strategies, and cutting‐edge applications in smart encryption, environmental sensing, and 3D printing. Abstract In recent years, photo‐controlled radical room‐temperature phosphorescent (RTP) materials have shown significant application ...
Sichen Meng   +8 more
wiley   +1 more source

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