Results 181 to 190 of about 434 (222)

Measuring Local Exothermic Effects During the Oxidative Coupling of Methane Using Operando Luminescence Thermometry

open access: yesAngewandte Chemie, EarlyView.
Operando luminescence thermometry shows that the local catalyst temperature can exceed the set oven temperature by almost 250°C during the exothermic oxidative coupling of methane process. We demonstrate how the reactor dimensions, catalyst grain size, and reactant feed mixture affect the local temperature.
Daniël W. Groefsema   +5 more
wiley   +2 more sources

Spatial Cell Death and Oxidative Stress Dynamics in Gas Plasma‐Treated Tumor Tissues

open access: yesAdvanced NanoBiomed Research, EarlyView.
Schematic representation of the four experimental models to study tissue penetration and oxidation. Four tissue models were used. Human pancreatic cancer cells were grown on the chorioallantois membrane of chicken embryos and gas plasma‐treated in ovo, murine colorectal tumor tissue was gas plasma‐exposed ex vivo, murine squamous cell carcinoma cells ...
Anke Schmidt   +4 more
wiley   +1 more source

Crosslinking of Linear Polyimines Into Aminal‐Linked Porous Organic Polymers for C2 Hydrocarbon/Methane Separation

open access: yesAngewandte Chemie, EarlyView.
Crosslinking of linear polyimines with aromatic diamines via nucleophilic addition converts nonporous polyimine precursors into aminal‐linked porous networks, offering a new strategy for synthesizing porous organic polymers. The resulting materials exhibit high C2 hydrocarbon adsorption capacity, excellent selectivity over CH4, and durable cyclic ...
Xuejie Li   +4 more
wiley   +2 more sources

On the Cranial Nerves. [PDF]

open access: yesNeuroSci
Libreros-Jiménez HM   +9 more
europepmc   +1 more source

Injectable Bone Cements: A Generational Framework for Bioactivity, Porosity, and Mechanobiological Design at the Nanoscale

open access: yesAdvanced NanoBiomed Research, EarlyView.
Key demographic, biological, and material considerations that drive the need for advanced injectable bone cement technologies. Injectable bone cements (IBCs) are widely used in orthopaedic and craniofacial applications due to their minimally invasive delivery and ability to provide early mechanical stabilisation.
Frank Fei   +2 more
wiley   +1 more source

1,7‐Digallatetracarborane: Between Nucleophilic closo‐Cluster and “Inverse Sandwich” Digallylene

open access: yesAngewandte Chemie, EarlyView.
A dianionic π‐ligand is used to make a Janus‐type twofold complex with low‐valent gallium Ga(+I). The resulting compound can be seen as and reveals the reactivity of both: a Wade‐type closo‐carborane cluster with nucleophilic Ga‐sites, as well as π‐ligand stabilized Ga(I) atoms in an inverse sandwich compound.
Julijan Sarcevic   +4 more
wiley   +2 more sources

Senolytic treatment does not mitigate oxidative stress-induced muscle atrophy but improves muscle force generation in CuZn superoxide dismutase knockout mice. [PDF]

open access: yesGeroscience
Borowik AK   +8 more
europepmc   +1 more source

Enhanced Formation of Dicarboxylic Acids in the Catalytic Oxidation of Polyethylene With O2 and NOx

open access: yesAngewandte Chemie, EarlyView.
The oxidation of polyethylene in the presence of a mixture of O2 and NOx and with Cu2+/V5+ as catalyst yields ∼51 mol% diacids, while retaining ∼80 mol% of the carbon in the oil fraction. The developed method is robust and tolerates several polymer types as well as impurities.
Tom J. Smak   +3 more
wiley   +2 more sources

Inverse Vulcanization Through Epoxide Chemistry: A Low Temperature Non‐Olefin Route to Sulfur‐Rich Polymer Networks

open access: yesAngewandte Chemie, EarlyView.
Epoxide monomers undergo base‐catalyzed ring‐opening copolymerization with elemental sulfur to afford sulfur‐rich polymers under mild conditions. The resulting materials exhibit excellent mechanical performance, strong adhesion (up to 10 MPa on stainless steel), and outstanding reprocessability.
Pan Yang   +5 more
wiley   +2 more sources

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