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We elucidate the key roles of metal p‐d orbital hybridization, excited‐state metal–ligand π‐interactions, and structural rotation in TADF of d10 CMA complexes. Introducing electron‐withdrawing or π‐extended ligand substituents weakens excited‐state metal‐ligand π‐interactions and improves kTADF, but may compromise emitter stability in device operation.
Shuo Xu +5 more
wiley +1 more source
Local stress concentration disrupts metabolic homeostasis and induces inflammation in the nucleus pulposus (NP), thereby accelerating intervertebral disc degeneration (IDD). A biomimetic HA/ChS hydrogel millimeter sphere (ChS@HM) is developed to enable synergistic stress dispersion and sustained hydration lubrication.
Ang Li +4 more
wiley +1 more source
Atroposelective Construction of Axially Chiral Tetraarylethenes Via NHC‐Catalyzed Desymmetrization
We report the first NHC‐catalyzed atroposelective synthesis of axially chiral TAEs via oxidative desymmetrization of prochiral TAE dialdehydes. This catalytic strategy operates under mild conditions and accommodates a broad range of phenolic and nitrogen nucleophiles, delivering diverse axially chiral TAEs in good yields and up to 99% ee.
Yang‐Ze Zheng +6 more
wiley +1 more source
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A "burn out" of occipital cortex
Minerva Anestesiologica, 2020None
Silva S. +5 more
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burn outIf we are lucky to get/ a quick pick-up, many of the men are"burned out" by a big cargo of sealskins, which takes up their bunk space.... [Sic. Error for turned out?
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Pediatrics, 1978
In a recent commentary in response to Anders' article,2 Rothenberg pointed out that individuals who have chosen pediatrics for any of these reasons [comfort with children rather than adults, need to be in control of patients, or reacting against basic dislike and discomfort with children] are obviously not going to be interested in ...
openaire +2 more sources
In a recent commentary in response to Anders' article,2 Rothenberg pointed out that individuals who have chosen pediatrics for any of these reasons [comfort with children rather than adults, need to be in control of patients, or reacting against basic dislike and discomfort with children] are obviously not going to be interested in ...
openaire +2 more sources
“Burning Out” versus “Punching Out”
Journal of Human Stress, 1980Abstract “Burning Out” among air traffic controllers is the syndrome of depression, anxiety, fear of a midair collision, insomnia, and inability to function professionally with confidence. Individuals who suffer such reactions are rapidly retired for medical reasons from air traffic control work.
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