Masked Silylenes: Controlled Generation and Reactivity Under Thermal and Equilibrium Conditions
European Journal of Inorganic Chemistry, EarlyView.This Review provides an overview of masked silylenes as bench‐stable precursors that release silylenes (R2Si:) under thermal activation or reversible equilibria. Precursor preparation, generation pathways, and characteristic reactivity are summarized, including trapping chemistry, reversible interconversions, insertion‐type processes, and small ...
Kei Ota, Kanata Miyahara, Norio Nakata
wiley +1 more source
Push–Pull Ynamines and Push–Pull Ynamides: Synthesis, Structure, Reactivity, and Application
European Journal of Organic Chemistry, EarlyView.Push–pull ynamines and push–pull ynamides, which carry an EWG and an amino or amido group as EDG, are highly interesting classes of EDG‐EWG alkynes that have been intensively studied due to their exceptional reactivity. In this review, the synthesis, structure, reactivity, and application of push–pull ynamines, push–pull ynecarbamates, push–pull ...
Hans‐Joachim Gais
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Ab-initio Dynamics of Rare Thermally Activated Reactions
, 2009 We introduce a framework to investigate ab-initio the dynamics of rare thermally activated reactions. The electronic degrees of freedom are described at the quantum-mechanical level in the Born-Oppenheimer approximation, while the nuclear degrees of ...
Beccara, S. a +3 more
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1,2‐Diazetidines − Structure, Synthesis, and Functionalization
European Journal of Organic Chemistry, EarlyView.1,2‐Diazetidines are saturated four‐membered heterocycles featuring two adjacent nitrogen atoms. Despite recent advances in their synthesis and promising potential in medicinal chemistry, the chemistry of these cyclic hydrazines remains underexplored.
Stefan Roesner
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Structural design and 3D printing of flexible integrated electronic systems
FlexMat, EarlyView.This review provides a comprehensive overview of design and integration strategies for individual components in flexible electronics, highlights the 3D‐printing fabrication techniques, and discusses recent advances in system‐level integration and their applications in real‐time monitoring and intelligent robotics.
Jiani Gong +8 more
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Understanding the Propagation Step in a Photoredox Cycloaddition Chain Reaction. [PDF]
ACS CatalLee AA +5 more
europepmc +1 more source
InfoMat, EarlyView.This work constructs a series of graphite anodes with systematically varied binder distribution, porosity, and electrode thickness to resolve the role of microstructural heterogeneity during fast charging. The digital twin framework reveals how phase‐level structural gradients govern Li plating, SEI formation, and diffusion‐induced stresses, providing ...
Yejin Kang +4 more
wiley +1 more source
Iron-Catalyzed Cross-[2 + 2] Cycloaddition of Butadiene and α,ω-Dienes for Ductile and Chemically Recyclable Poly(oligocyclobutanes). [PDF]
J Am Chem SocNie C +7 more
europepmc +1 more source
3D‐Printed Models in Oral Surgery Simulation Training: A Scoping Review
Journal of Dental Education, EarlyView.ABSTRACT Background Advancements in three‐dimensional (3D) printing have introduced innovative tools for medical and dental education. In dental surgery, 3D‐printed simulation models offer valuable presurgical training. This review explores the scope, study types, key findings, limitations, and future research needs to enhance their application in ...
Shahrzad Rahimizadeh Nahavandi +5 more
wiley +1 more source
Genotoxic exposures to volatile organic compounds in golden retrievers with and without multicentric lymphoma. [PDF]
Front Vet SciTindle AN +4 more
europepmc +1 more source