Results 41 to 50 of about 16,861 (181)

Polycarbonate Upcycling Into Block Copolymers via Transcarbonation: Influence of the Catalyst on the Microstructure

open access: yesChemistry – A European Journal, EarlyView.
Upcycling of polycarbonate (PC‐BPA) into PC‐BPA–polybutadiene (PBd) block copolymers was achieved by transcarbonation with hydroxytelechelic PBd (Krasol) using organic base catalysts. Catalyst choice governed conversion, molecular weight and microstructure: TBD produced multiblock copolymers, whereas DMAP yielded higher Mn materials with lower ...
N. Kanso   +5 more
wiley   +1 more source

Development of Cellulosic Bioplastic‐Based Biocomposites for Biodegradable Packaging Applications: Effect of High Acetyl Content and High Filler Loading

open access: yesPolymer Engineering &Science, EarlyView.
Schematic representation of the development of cellulosic bioplastic‐based biocomposites via reactive extrusion and injection molding, demonstrating improved oxygen and water vapor barrier properties for biodegradable packaging applications. ABSTRACT Cellulosic bioplastics have attained significant interest because of their biodegradability and ...
Reshma Krishnan   +2 more
wiley   +1 more source

Isothermal Crystallization Kinetics and Crystalline Morphologies of Poly(butylene adipate-co-butylene 1,4-cyclohexanedicarboxylate) Copolymers

open access: yes, 2018
In this study, the isothermal crystallization kinetics and crystalline morphology of poly(butylene adipate-co-butylene 1,4-cyclohexanedicarboxylate) (PBAC), which refers to a copolyester containing a non-planar ring structure, were investigated by ...
Zhu, Jin   +3 more
core   +1 more source

Electrospun conducting polymers: recent trends and the transition towards a sustainable future

open access: yesPolymer International, EarlyView.
This review discusses the electrospinning of conducting polymers, detailing procedures, fibrous morphologies, improved properties, applications in electronics, and challenges, while outlining future directions for nanofibre‐based devices in various fields.
Xenofon Karagiorgis   +3 more
wiley   +1 more source

Difluoromethylenation of Alkynes: Streamlined Access to Allyl Difluorides

open access: yesAngewandte Chemie, Volume 138, Issue 46, 9 November 2026.
Stabilizing primary oxocarbenium in HF/pyridine unlocks a direct alkyne difluoromethylenation – an efficient route to synthetically‐relevant allyl difluorides in a single step. ABSTRACT A direct difluoromethylenation of alkynes has been developed using HF/pyridine as a dual acidic and fluorinating medium. The reaction proceeds via in situ generation of
Fabien Naullet   +4 more
wiley   +2 more sources

Unsaturated biobased polyesters from bicyclic α‐pinene‐based diols

open access: yesPolymer International, EarlyView.
We present the synthesis of four biosourced unsaturated polyesters made from chiral terpene‐based diols and esters of renewable diacids. The resulting materials harbor a bicyclic pinene ring in their backbones which leads to enhanced thermal properties while still conferring susceptibility to enzyme hydrolysis for chains having a cis alkene.
Ganapathy Ranjani   +4 more
wiley   +1 more source

Extruder‐based 3D printing of eco‐friendly polymers

open access: yesPolymer International, EarlyView.
Eco‐friendly polymers, such as biodegradable and recycled materials, offer significant potential for the production of high‐quality 3D‐printed components, provided that their properties and characteristics meet the requirements of extruder‐based 3D printing.
Rui Zhang   +7 more
wiley   +1 more source

Separation of glycols from dilute aqueous solutions via complexation with boronic acids [PDF]

open access: yes, 1991
This work examines methods of separating low molecular weight glycols from dilute aqueous solution. Extraction into conventional solvents is generally not economical, since, in the literature reviewed, distribution ratios for the two- to four-carbon ...
Randel, L.A.   +3 more
core   +1 more source

Copolymer Synthesis of N‐Vinylacetamide and 2‐Methylene‐1,3‐Dioxepane Provides a New Degradable Polymer

open access: yesJournal of Polymer Science, Volume 63, Issue 6, Page 1306-1318, 15 March 2025.
ABSTRACT N‐vinylamides, especially noncyclic N‐vinylacetamide (NVA), have been used in various applications such as biomaterials, surfactants, and hydrogels. However, their potential to copolymerize with cyclic ketene acetal (CKA) to create degradable polymers is underexplored.
Mukmin Sapto Pamungkas   +2 more
wiley   +1 more source

Antibacterial and antifungal properties of propylene glycol, hexylene glycol, and 1,3-butylene glycol in vitro.

open access: yesActa Dermato-Venereologica, 1991
The antimicrobial properties of three glycols, - propylene glycol, hexylene glycol, and 1,3-butylene glycol - against Candida albicans, Staphylococcus aureus, Staphylococcus epidermidis, Streptococcus pyogenes A, Streptococcus mitis, and E. coli were studied in vitro. Within 20 h, 10% and 30% hexylene glycol in fresh tryptic soy broth were able to kill
T, Kinnunen, M, Koskela
openaire   +2 more sources

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