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Cyanoisocyanoacetylene, N≡C−C≡C−N≡C

Angewandte Chemie International Edition, 1998
Vacuum pyrolysis of the precursor complex [(CO)5 Cr(CN-CCl=CF-CN)] resulted in the isolation and structure elucidation by molecular spectroscopy of isomer 1. According to ab initio calculations 1 is 109 kJ mol-1 less stable than NC-C≡C-CN, which has been known for some time.
Christoph, Bartel, Peter, Botschwina, Hans, Bürger, Antonio, Guarnieri, Änne, Heyl, Aiko, Huckauf, Dieter, Lentz, Tatjana, Merzliak, El Bachir, Mkadmi   +8 more
openaire   +2 more sources