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Understanding and Exploiting C—H Bond Activation
ChemInform, 2002AbstractFor Abstract see ChemInform Abstract in Full Text.
Labinger, Jay A., Bercaw, John E.
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Towards mild metal-catalyzed C–H bond activation
Chemical Society Reviews, 2011Functionalizing traditionally inert carbon-hydrogen bonds represents a powerful transformation in organic synthesis, providing new entries to valuable structural motifs and improving the overall synthetic efficiency. C-H bond activation, however, often necessitates harsh reaction conditions that result in functional group incompatibilities and limited ...
J. Wencel-Delord +3 more
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Metal-catalysed C–H bond activation and borylation
Chemical Society Reviews, 2022Transition metal-catalysed direct borylation of hydrocarbons via C–H bond activation has received a remarkable level of attention as a popular reaction in the synthesis of organoboron compounds owing to their synthetic versatility.
Ranjana Bisht +5 more
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CH Bond Activation by f‐Block Complexes
Angewandte Chemie International Edition, 2014AbstractMost homogeneous catalysis relies on the design of metal complexes to trap and convert substrates or small molecules to value‐added products. Organometallic lanthanide compounds first gave a tantalizing glimpse of their potential for catalytic CH bond transformations with the selective cleavage of one CH bond in methane by bis ...
Polly L, Arnold +3 more
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Journal of the American Chemical Society, 2023
Double C-H bond activation can enable an expeditious reaction pathway to cyclic compounds, offering an efficient tool to synthesize valuable molecules.
Yongzheng Ding, Jianing Wu, Hanmin Huang
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Double C-H bond activation can enable an expeditious reaction pathway to cyclic compounds, offering an efficient tool to synthesize valuable molecules.
Yongzheng Ding, Jianing Wu, Hanmin Huang
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ChemInform, 2004
AbstractFor Abstract see ChemInform Abstract in Full Text.
Fumitoshi Kakiuchi, Naoto Chatani
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AbstractFor Abstract see ChemInform Abstract in Full Text.
Fumitoshi Kakiuchi, Naoto Chatani
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Rhodium-Catalyzed Atroposelective Construction of Indoles via C-H Bond Activation.
Angewandte Chemie, 2020Reported herein is the rhodium(III)-catalyzed C-H activation of anilines bearing an N -isoquinolyl directing group for oxidative [3+2] annulation with four classes of internal alkynes, leading to atroposelective indole synthesis via dynamic kinetic ...
Lincong Sun +7 more
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Graphene-based Photonic C-H bond activation
Frontiers in Optics + Laser Science 2021, 2021C-H bond activation is critical for the realization of photosynthesis. We present a graphene-based spectroscopic technique (J. Phys. Chem. C 2021, 125, 7, 3811) [1] that controls the C-H bond Raman modes allowing for the study of thermodynamic changes at the molecular level.
Erick Ulin-Avila, Akhilesh Kumar Mishra
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Iridium‐Catalyzed Hydroarylation via C−H Bond Activation
The Chemical Record, 2021AbstractHydroarylation reactions via C−H activation, which compensate for shortcomings of classical methods based on the Friedel‐Crafts reaction, is one of the most attractive methods to synthesize substituted arenes. This Personal Account reviews our recent studies on iridium‐catalyzed intermolecular hydroarylation of vinyl ethers, alkynes ...
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Metal-Organic Framework (MOF)-Based Materials as Heterogeneous Catalysts for C-H Bond Activation.
Chemistry, 2018Converting light hydrocarbons such as methane, ethane, propane, and cyclohexane into value-added chemicals and fuel products by means of direct C-H functionalization is an attractive method in the petrochemical industry.
Mengjia Liu, Jie Wu, H. Hou
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