Total Synthesis of Dactyloquinone A and Spiroetherone A via a Metal-Hydride Hydrogen Atom Transfer (MHAT) Process and a Quinol-Enedione Rearrangement. [PDF]
Total syntheses of the meroterpenoid quinones dactyloquinone A and spiroetherone A were achieved from a common intermediate through the following original key steps: a metal‐hydride hydrogen atom transfer (MHAT) process with a quinone monoacetal in the case of dactyloquinone A, and a quinol–enedione rearrangement in the case of spiroetherone A ...
Schoenn G +4 more
europepmc +3 more sources
Diverse and mobile: eccDNA-based identification of carrot low-copy-number LTR retrotransposons active in callus cultures. [PDF]
SUMMARY Long terminal repeat retrotransposons (LTR‐RTs) are mobilized via an RNA intermediate using a ‘copy and paste’ mechanism, and account for the majority of repetitive DNA in plant genomes. As a side effect of mobilization, the formation of LTR‐RT‐derived extrachromosomal circular DNAs (eccDNAs) occurs.
Kwolek K +6 more
europepmc +2 more sources
Secondary metabolites from plant-associated Pseudomonas are overproduced in biofilm. [PDF]
Pseudomonas strains overproduce a higher diversity of secondary metabolites in biofilm colony than in planktonic lifestyle. In particular, the biosynthesis of key compounds implicated in bacterial biotic interactions like AHLs or phenazines are strongly enhanced in biofilms.
Rieusset L +7 more
europepmc +2 more sources
HadBD dehydratase from Mycobacterium tuberculosis fatty acid synthase type II: A singular structure for a unique function. [PDF]
Abstract Worldwide, tuberculosis is the second leading infectious killer and multidrug resistance severely hampers disease control. Mycolic acids are a unique category of lipids that are essential for viability, virulence, and persistence of the causative agent, Mycobacterium tuberculosis (Mtb).
Bories P +14 more
europepmc +2 more sources
5‐Hydroxymethylfurfural and Furfural Chemistry Toward Biobased Surfactants
Sustainable surfactants: Furanic platform molecules can lead to novel biobased surfactants with original molecular design. In this Review, synthetic strategies from of 5‐hydroxymethylfurfural, furfural, and furan leading to anionic, cationic, amphoteric, and non‐ionic amphiphiles are highlighted.
Xiaoyang Yue, Yves Queneau
wiley +1 more source
Essential Oils in Stored Product Insect Pest Control
Among botanical extracts used as insecticides, essential oils (EOs) are promising alternatives to chemical insecticides. EOs are synthesized by plants, and they play a key role in plant signaling processes including also attractiveness toward pollinators and beneficial insects.
Orlando Campolo +5 more
wiley +1 more source
ABSTRACT Compared to large enterprises (LEs), small and medium‐sized enterprises (SMEs) have unique characteristics that may affect their needs in several areas. Thus, the “one‐size‐fits‐all” approach to meeting the needs of both groups of enterprises would be inappropriate in different circumstances.
Sylvestre Uwizeyemungu, Jacques Bertrand
wiley +1 more source
A Promising Approach to Target Colorectal Cancer Using Hybrid Triarylmethanes
Exploration of novel anti‐colorectal cancer agents: This study focuses on hybrid triarylmethane compounds and their N‐oxide analogues. Pyridine N‐oxide hybrids showed significant antiproliferative activity on HT‐29 and HCT116 cell lines, with IC50 values between 18 and 24 μM.
Ameni Hadj Mohamed +8 more
wiley +1 more source
Qualité des restaurations réalisées au service d'odontologie de Clermont-Ferrand : influence du site et du stade de la lésion, de l’année de l’étudiant et du matériau [PDF]
Le but principal de cette étude est de repérer quels sont les facteurs, matériau, site et stade lorsqu’il s’agit de lésions carieuses, et de l’année d’étude de l’étudiant, impactant la qualité des restaurations réalisées au sein du service d’odontologie ...
Baek, Hye Min
core
Quelle intégration pour les requérants d'asile mineurs non accompagnés en Valais [PDF]
L’accueil et l’intégration des personnes migrantes est un enjeu sociétal actuel. Le canton du Valais a mis sur pied la structure du RADOS, institution destinée à l’accompagnement spécifique des mineurs non accompagnés.
Gay, Marcelle, Zenhausern, Déborah
core

