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Polyhedral Oligomeric Silsesquioxanes Based Ultralow‐k Materials: The Effect of Cage Size
Advanced Functional Materials, 2021Polyhedral oligomeric silsesquioxanes (POSS) are of considerable interest as building blocks for preparing low‐k materials. To date T8 POSS has been extensively investigated while the potential of larger POSS cages remain an unexplored area.
Dai‐Lin Zhou +7 more
semanticscholar +1 more source
Nature Reviews Chemistry, 2021
Homochiral porous cage-in-cage structures that self-assemble from lanthanide cations and chiral amino acid-derived ligands have been prepared and shown to be highly effective in enantioselective separations of small-molecule guests.
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Homochiral porous cage-in-cage structures that self-assemble from lanthanide cations and chiral amino acid-derived ligands have been prepared and shown to be highly effective in enantioselective separations of small-molecule guests.
openaire +2 more sources
Highly efficient catalysis of the Kemp elimination in the cavity of a cubic coordination cage
Nature Chemistry, 2016William M Cullen +2 more
exaly +2 more sources
Homochiral Dodecanuclear Lanthanide "Cage in Cage" for Enantioselective Separation.
Journal of the American Chemical Society, 2021It is extremely difficult to anticipate the structure and the stereochemistry of a complex, particularly when the ligand is flexible and the metal node adopts diverse coordination numbers.
Chengfeng Zhu +9 more
semanticscholar +1 more source
ChemInform, 2005
Various cages are constructed by using three types of caps: f-cap (derived from spherical fullerenes by deleting zones of various size), kf-cap (obtainable by cutting off the polar ring, of size k), and t-cap ("tubercule"-cap). Building ways are presented, some of them being possible isomerization routes in the real chemistry of fullerenes.
Diudea, M.V. +5 more
openaire +3 more sources
Various cages are constructed by using three types of caps: f-cap (derived from spherical fullerenes by deleting zones of various size), kf-cap (obtainable by cutting off the polar ring, of size k), and t-cap ("tubercule"-cap). Building ways are presented, some of them being possible isomerization routes in the real chemistry of fullerenes.
Diudea, M.V. +5 more
openaire +3 more sources
Cage‐to‐Cage Cascade Transformations
Chemistry – A European Journal, 2016AbstractA series of Pd2L4‐type binuclear self‐assembled coordination cages (1–4), where L stands for a nonchelating bidentate ligand, were prepared. The strategies adopted for the synthesis of the cages were: combination of PdII with 1) a selected ligand or 2) subcomponents of the ligand.
Sreenivasulu, Bandi, Dillip Kumar, Chand
openaire +2 more sources
Spine, 2020
STUDY DESIGN A retrospective cohort study. OBJECTIVE To determine the risk factors of cage subsidence in patients undergoing minimally invasive transforaminal lumbar interbody fusion (MI-TLIF) and its correlation with patient-reported outcomes ...
Yu-Cheng Yao +5 more
semanticscholar +1 more source
STUDY DESIGN A retrospective cohort study. OBJECTIVE To determine the risk factors of cage subsidence in patients undergoing minimally invasive transforaminal lumbar interbody fusion (MI-TLIF) and its correlation with patient-reported outcomes ...
Yu-Cheng Yao +5 more
semanticscholar +1 more source
Cage-like silsesquioxanes-based hybrid materials.
Dalton Transactions, 2020Cage-like silsesquioxanes are considered to be ideal and versatile building blocks of hybrid materials due to their unique structures and excellent performance.
Yajing Du, Hongzhi Liu
semanticscholar +1 more source
ChemInform, 2003
AbstractFor Abstract see ChemInform Abstract in Full Text.
Vickie, McKee +2 more
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AbstractFor Abstract see ChemInform Abstract in Full Text.
Vickie, McKee +2 more
openaire +2 more sources
Journal of the American Chemical Society, 2019
Chiral lanthanide cages with circularly polarized luminescence (CPL) properties have found potential application in enantiose-lective guest recognition and sensing.
Yanyan Zhou +4 more
semanticscholar +1 more source
Chiral lanthanide cages with circularly polarized luminescence (CPL) properties have found potential application in enantiose-lective guest recognition and sensing.
Yanyan Zhou +4 more
semanticscholar +1 more source

