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Calcium Carbide (CaC2) as a C2-Synthon by Mechanochemistry.
ChemPlusChemMechanochemical reactions by ball milling have opened new avenues in chemical synthesis. Particularly, mechanochemistry has facilitated the reaction of insoluble materials to simplify stablished synthetic protocols and develop new ones.
Alejandro Cortés‐Lobo +1 more
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A simple method for the synthesis of (Z)‐3‐benzylidene‐2‐(quinolin‐8‐yl)isoindolin‐1‐ones through C(sp2)−H bond activation, Sonogashira cross‐coupling and annulation tandem reactions using calcium carbide as a solid alkyne source, and benzamides as ...
Fei Wen +8 more
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A simple method for the synthesis of (Z)‐3‐benzylidene‐2‐(quinolin‐8‐yl)isoindolin‐1‐ones through C(sp2)−H bond activation, Sonogashira cross‐coupling and annulation tandem reactions using calcium carbide as a solid alkyne source, and benzamides as ...
Fei Wen +8 more
semanticscholar +1 more source
Phase Relationships in the Calcium Chloride – Calcium Carbide System
Canadian Journal of Chemistry, 1972The system calcium chloride – calcium carbide has been examined by thermal analysis. The depression of the freezing point of CaCl2 by CaC2 is ideal. The system is a eutectic one, with a eutectic point at 90 mol% CaCl2 at 740 °C. Carbon is believed to be present in the electrolyte as the so called acetylide ion [Formula: see text] The melting point of ...
J. F. Maillot, D. R. Morris
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Thermodynamic Analysis of Calcium Carbide Production
Industrial & Engineering Chemistry Research, 2014CaC2 production is studied from the viewpoint of thermodynamics using an equilibrium composition model with total Gibbs free energy minimization. It is found that CaC2 is formed directly from the reaction of C and CaO without an intermediate step under the conditions of industrial practice.
Leiming Ji, Qingya Liu, Zhenyu Liu
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Reduction-carbidization of titanium oxide by calcium hydride and calcium carbide
Soviet Powder Metallurgy and Metal Ceramics, 1988V. I. Kotenev +3 more
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