Results 201 to 210 of about 426,170 (291)

Mechanical Caging of Nucleic Acids Enabled by Light‐Activated Synthetic Molecular Motors

open access: yesAngewandte Chemie, EarlyView.
A synthetic light‐driven molecular motor imposes mechanical constraints on nucleic acids, enabling “mechanical caging” as a new mode to regulate DNA structure and function through mechanical input rather than chemical masking. ABSTRACT Control over nucleic acid activity is central to biotechnology and therapeutic development.
Yuchen Ma   +10 more
wiley   +2 more sources

Record Dissymmetry in Vibrational Optical Activity: Combining Vibronic Coupling and Aggregation in Cobalt(II) Camphorate Complexes

open access: yesAngewandte Chemie, EarlyView.
The cobalt(II) bis(trifluoroacetylcamphorate) scaffold exhibits versatile coordination chemistry with solvent‐driven ligand exchange and geometrical rearrangements, associated with unique chiroptical properties. Microcrystalline suspension of [Co(tfc)2(CH3CN)2] revealed the largest VCD dissymmetry factor ever reported (g ≈ 0.2 at 1600 cm−1), arising ...
Gianmarco Papi   +4 more
wiley   +2 more sources

Impact of Thermocycling and Artificial Aging on the Flexural Strength and Fracture Resistance of CAD/CAM Dental Ceramics: A Systematic Review and Meta-Analysis. [PDF]

open access: yesDent J (Basel)
Mora Bayas JM   +12 more
europepmc   +1 more source

Ambiphilic Ligand Stabilization of Aluminum(I) Fragments: Halides, Cations, and a Hydride

open access: yesAngewandte Chemie, EarlyView.
Stabilization of elusive aluminum(I) halides in the framework of an ambiphilic ligand is reported. The unique bonding situation at the trigonal‐bipyramidal aluminum center is analyzed, and the coordination chemistry and Al(I)Br transfer reactivity of the complexes are presented.
Charlotte S. V. Weiß   +1 more
wiley   +2 more sources

Characterizing the Epithelial Transcriptome of Type‐2 High Chronic Rhinosinusitis

open access: yes
International Forum of Allergy &Rhinology, EarlyView.
Brian Cameron   +7 more
wiley   +1 more source

Molecular Basis for Activation to Inhibition Switching in Kv7.2 Channel Modulators

open access: yesAngewandte Chemie, EarlyView.
The paper describes the serendipitous discovery of chemical manipulation allowing the activator‐to‐inhibitor switching in Kv7.2 channel modulators. The molecular determinants driving this switch have been rationalized by multidisciplinary investigation encompassing synthetic and analytical chemistry, in silico methods, cryo‐EM analysis ...
Tania Ciaglia   +20 more
wiley   +2 more sources

Comparative Evaluation of Push-Out Bond Strength Between CAD/CAM-Milled and Anatomically Customized Fiber Posts: An In Vitro Study. [PDF]

open access: yesInt J Dent
Gusmão COA   +7 more
europepmc   +1 more source

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