Results 141 to 150 of about 52,149 (242)

π‐Radical Cascades to Peri‐Fused Triangulene Dimers

Angewandte Chemie, EarlyView.
We demonstrate the potential of open‐shell molecular graphene fragments as synthons for constructing graphene nanostructures via π‐radical cascades. By identifying monoradical intermediates as key selectivity‐determining species and tuning steric effects in a triangulene precursor, we show that reactivity in a formally diradical system can be ...
Paula L. Widmer, Leoš Valenta, Maximilian Mayländer, Jules Hutter, Francis J. Carta, Simon Jurt, Olivier Blacque, Laurent Bigler, Sabine Richert, Tomáš Šolomek, Michal Juríček   +10 more
wiley   +2 more sources

Iron‐Photocatalyzed C(sp3)–H Phosphonylation of Alkanes

Angewandte Chemie, EarlyView.
Alkyl phosphonates are valuable motifs that can be prepared by phosphonylations of various common functional groups. However, direct phosphonylations of C(sp3)–H bonds are limited to activated positions. Herein, we report an iron‐photocatalyzed phosphonylation of unactivated C(sp3)–H bonds using a novel phosphite radical trap, which is equipped with an
Ya Dong, Wangyujing Han, Hanwen Zhang, Santosh K. Pagire, Harry Meats, Adam Noble, Varinder K. Aggarwal   +6 more
wiley   +2 more sources

Single‐Atom Iron‐Catalyzed Oxidative Esterification: From Methylarenes to the Upcycling of Polystyrene and Lignin‐Derived Feedstocks

Angewandte Chemie, EarlyView.
Heterogeneous iron‐catalyzed environmentally benign and sustainable CH‐oxidative esterification methodology has been developed for the synthesis of esters. This challenging reaction has been achieved by the rational design of specific single atom iron‐based catalyst with Fe‐N4 active centers, which empowered the oxidative esterification of methyl and ...
Zhuang Ma, Binyu Zhang, Hui Yang, Yue Hu, Junzheng Yu, Yanbin Cui, Jun Zhao, Matthias Beller, Rajenahally V. Jagadeesh   +8 more
wiley   +2 more sources

Rapid shift in methane carbon isotopes suggests microbial emissions drove record high atmospheric methane growth in 2020-2022. [PDF]

Proc Natl Acad Sci U S A
Michel SE, Lan X, Miller J, Tans P, Clark JR, Schaefer H, Sperlich P, Brailsford G, Morimoto S, Moossen H, Li J.   +10 more
europepmc   +1 more source

Including Stable Carbon Isotopes to Evaluate the Dynamics of Soil Carbon in the Land-Surface Model ORCHIDEE. [PDF]

J Adv Model Earth Syst, 2019
Camino-Serrano M, Tifafi M, Balesdent J, Hatté C, Peñuelas J, Cornu S, Guenet B.   +6 more
europepmc   +1 more source

Toarcian oceanic anoxic event: An assessment of global causes using belemnite C isotope records

, 2005
Two hypotheses have been proposed to explain simultaneous large negative excursions (up to 7% PeeDee belemnite) in bulk carbonate (delta(13)C(carb)) and organic carbon isotope records (delta(13)C(org)) from black shales marking the Toarcian oceanic ...
van de Schootbrugge, B, Rosenthal, Y, Miller, KG, Bailey, TR, Wright, JD, McArthur, JM   +5 more
core  

Estimating the heritability of nitrogen and carbon isotopes in the tail hair of beef cattle. [PDF]

Genet Sel Evol
Moradi M, Warburton CL, Porto-Neto LR, Silva LFP.   +3 more
europepmc   +1 more source

Redirecting Excited‐State Proton Transfer Through Supramolecular Polymerization in Nanoconfinement

Angewandte Chemie, EarlyView.
Supramolecular confinement redirects the excited‐state proton transfer pathway of an amphoteric emitter. In water, the molecule undergoes ESPD, whereas co‐assembly with γ‐cyclodextrin forms nanotubes that template slip‐stacked emitter pairs and enable ESIMPT. Structural and photophysical characterization of the assemblies shows that the preorganization
Luis C. Pantaleone, Robert Hutchings, Bente Reus, Jacopo Martinelli, Alessia Lasorsa, Patrick C. A. van der Wel, Marc C. A. Stuart, Wesley R. Browne, Tibor Kudernac   +8 more
wiley   +2 more sources

Helium, inorganic and organic carbon isotopes of fluids and gases across the Costa Rica convergent margin. [PDF]

Sci Data, 2019
Barry PH, Nakagawa M, Giovannelli D, Maarten de Moor J, Schrenk M, Seltzer AM, Manini E, Fattorini D, di Carlo M, Regoli F, Fullerton K, Lloyd KG.   +11 more
europepmc   +1 more source

Unlocking a Nitrosuccinate Lyase for Decarboxylative Enzymatic Hydronitration

Angewandte Chemie, EarlyView.
The nitrosuccinate lyase CreD catalyzes C–NO2 bond formation using nitrite in water and shows synthetic practicality with high turnover numbers up to 102,000. A combination of protein engineering and computational methods helped to reveal the mechanistic principles that underpin this unique enzymatic activity.
Matteo Aleotti, Hannah Dreisbach, Rémi Corlay, Clara Weber, Tamara Reiter, Wael Elaily, Bastian Daniel, Klaus Zangger, Pedro A. Sánchez‐Murcia, Mélanie Hall   +9 more
wiley   +2 more sources