Angewandte Chemie, EarlyView.A photoswitchable ligand was used to trigger conformational changes within the thrombin binding aptamer DNA G‐Quadruplex. These reversible ligand driven rearrangements were examined by time‐resolved NMR experiments to gain insight of the dynamic folding landscape of the G‐quadruplex.
Jason Martins +2 more
wiley +2 more sources
Tracing CO2 sources in urban and rural areas characterized by different land-use patterns using carbon isotopes. [PDF]
PLoS OneJeong EK +5 more
europepmc +1 more source
Template‐Encoded Assembly and Adaptive Function in Selenium‐Based Molybdenum Chalcoxide Rings
Angewandte Chemie, EarlyView.External templates write structural information into Se‐containing molybdenum rings, while selenium's softness confers adaptive host–guest behaviour and catalytic responsiveness, an integrated framework for programmable inorganic function. ABSTRACT Controlling both structure and function in inorganic self‐assembly remains a major challenge.
Giulia Pellegrino +4 more
wiley +2 more sources
Correction: Expansion of forest cover and coeval shifts in Later Stone Age land-use at Taforalt and Rhafas Caves, Morocco, as inferred from carbon isotopes in ungulate tooth enamel. [PDF]
PLoS OneWorthey KB +7 more
europepmc +1 more source
One‐Pot Biphasic Photocatalytic CO2‐to‐Carbonylation Cascades
Angewandte Chemie, EarlyView.Bioinspired biphasic compartmentalization enables one‐pot cascades where photocatalytic CO2 reduction generates CO for carbonylative cross‐couplings to synthesize complex organic products, including a pharmaceutical. ABSTRACT Photosynthesis compartmentalizes reactions across the thylakoid membrane in vivo to upcycle CO2 into complex chemicals that are ...
Sampurna Mitra +3 more
wiley +2 more sources
Amino acid stable carbon isotopes in nail keratin illuminate breastfeeding and weaning practices of mother - infant dyads. [PDF]
Amino AcidsSalahuddin H +2 more
europepmc +1 more source
Angewandte Chemie, EarlyView.Mesopore geometry programs the working‐state interface of Fe single sites during nitrate electroreduction. Hexagonal channels reorganize interfacial water and accompany the reversible evolution of isolated Fe─O4‐like sites toward Fe─O─Fe‐like motifs, promoting successive hydrogenation toward NH3 with a Faradaic efficiency of 99.1%.
Xiangyang Liu +8 more
wiley +2 more sources
Expansion of forest cover and coeval shifts in Later Stone Age land-use at Taforalt and Rhafas Caves, Morocco, as inferred from carbon isotopes in ungulate tooth enamel. [PDF]
PLoS OneWorthey KB +7 more
europepmc +1 more source
Angewandte Chemie, EarlyView.Fungal modular polyketide synthases (PKSs) remain largely unexplored. Functional characterization of the LasC/LasD assembly line established its role in strasseriolide C biosynthesis and suggested an unexpected strategy for chain initiation, in which a malonyl unit is transferred from the module 2 acyl carrier protein (ACP) domains to the loading ACP ...
Qiaolin Ji +5 more
wiley +2 more sources
Rapid shift in methane carbon isotopes suggests microbial emissions drove record high atmospheric methane growth in 2020-2022. [PDF]
Proc Natl Acad Sci U S AMichel SE +10 more
europepmc +1 more source