Results 131 to 140 of about 9,086 (206)

Beyond Activity: The Unified Framework of the Sabatier Principle to Guide Rational Design of Durable and Active Electrocatalysts

open access: yesCarbon Energy, EarlyView.
In this review, a unified framework of the Sabatier principle is applied to a diverse range of catalytic and electrocatalytic systems for advanced clean energy technologies, with a particular focus on the oxygen reduction reaction (ORR). This approach will guide the design and development of highly active and stable catalysts for fuel cells ...
Wanying Zhang   +6 more
wiley   +1 more source

Eco‐Friendly Synthesis of Cobalt Phthalocyanine for High‐Efficiency CO2${\rm CO}_{2}$ Electroreduction

open access: yesChemistry – A European Journal, EarlyView.
A sustainable synthesis of cobalt phthalocyanine (CoPc) using low‐impact solvents yields high‐performance electrocatalysts with reduced waste (E‐factor 18.6). When integrated into gas diffusion electrodes, CoPc achieves up to 12% Faradays efficiency for CO2‐to‐methanol and 65% CO2‐to‐CO conversion, aligning with state‐of‐the‐art materials and enabling ...
Gloria Zanotti   +10 more
wiley   +1 more source

Sunlight‐Driven Green Synthesis of Platinum Nanoparticles From Double‐Vacancy Halide Perovskite Precursors for Methanol Reforming

open access: yesChemistry – A European Journal, EarlyView.
ABSTRACT The development of synthetic procedures for preparing metal nanoparticles with controlled size using sunlight opens new avenues toward more sustainable methods with lower energy consumption. Herein, we propose the use of double‐vacancy halide perovskites as precursors for engineering highly crystalline and small platinum nanoparticles (< 3 nm)
Kevin Mego   +4 more
wiley   +1 more source

Living Microbial Drugs

open access: yesChemistry – A European Journal, EarlyView.
The introduction outlines the review scope. Microbial cell factories as living drugs cover host–gut microbiota, bacteria, yeast, and other microbial systems, with comparative host advantages. Engineering strategies include synthetic circuits, quorum sensing, and memory.
Cemile Elif Özçelik   +3 more
wiley   +1 more source

[Ti(py)4I2] as an Entry Point to Titanium(II) Chemistry via Titanium Metal Oxidation

open access: yesChemistry – A European Journal, EarlyView.
A strategically novel approach based on the oxidation of Ti metal enables access to Ti(II) chemistry. Controlled formation and complexation of Ti diiodide affords the Ti(II) complex [Ti(py)4I2], which serves as a convenient entry point to Ti(II) compounds.
Alexander Sedykh
wiley   +1 more source

Cross‐Carboxylation of Methanol and Other Alcohols With CO2 Into Asymmetric Alkyl Methyl Carbonates Over a CeO2 Catalyst

open access: yesChemistry – A European Journal, EarlyView.
One‐pot synthesis of asymmetric organic carbonates from CO2, methanol, and other alcohols was demonstrated in the presence of CeO2 catalyst and 2‐cyanopyridine dehydrant. This reaction proceeded through two reaction pathways—direct route via cross‐carboxylation and indirect route via production of DMC and subsequent transesterification.
Yuan Li   +4 more
wiley   +1 more source

Mechanochemical Amidation Mediated by 1,1’‐Oxalyldiimidazole for the Synthesis of Agrochemicals

open access: yesChemistry – A European Journal, EarlyView.
Mechanochemical amidation using 1,1'‐oxalyldiimidazole (ODI) overcomes limitations of 1,1’‐carbonyl diimidazole (CDI) as coupling agent by enabling the efficient mechanochemical synthesis of three marketed agrochemicals from deactivated carboxylic acids.
Andrea Casagrande   +6 more
wiley   +1 more source

Heteroatom‐Doped Graphdiynes and Their Applications in Photo‐/Electro‐Catalytic CO2 Conversion

open access: yesCarbon Innovation, EarlyView.
This review highlights the versatile role of doped graphdiyne (GDY) in boosting CO2 conversion, where metal and non‐metal doping simultaneously tune the electronic structure, create abundant active sites, and improve charge separation, light harvesting, and CO2 adsorption.
Fangzhou Yang   +3 more
wiley   +1 more source

Exploring Tradeoffs in Syngas Production With Solid‐Oxide Electrolysis via Multi‐Objective Optimization

open access: yesChemie Ingenieur Technik, EarlyView.
This work applies multi‐objective optimization to investigate trade‐offs between different objectives in syngas production with solid‐oxide cell co‐electrolysis. Two system designs are investigated. By systematically exploring tradeoffs between different objectives, insights, and comparisons of the operation of these designs are achieved.
Gbenga Jerome   +6 more
wiley   +1 more source

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