Results 171 to 180 of about 134,803 (296)

Ag‐Regulated Cu‐Sites on a Conductive Cu‐Metal‐Organic Framework for Enhanced CO2 Electroreduction to CH4

open access: yesEcoEnergy, EarlyView.
We present a strategy of integrating Ag NPs with a 2D Cu3(HHTP)2 framework to boost selective CO2 electroreduction. The optimal composite achieves 65.1% FECH4 ${\text{FE}}_{{\text{CH}}_{4}}$ at 240 mA cm−2. Synergistic effects enhance CO2 adsorption, facilitate electron transfer, and selectively stabilize key reaction intermediates, steering the ...
Fang‐Fang Wang   +3 more
wiley   +1 more source

Developing a Suitable Anion Exchange Layer Structure for Pure–Water Fed Bipolar Membrane CO2 Electrolysis

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
A porous anion exchange layer (AEL) is implemented in a forward‐biased bipolar membrane CO2 electrolyzer to suppress carbonate crossover, support CO2 regeneration and maintain cathode alkalinity. Two fabrication strategies are compared—deposition on a silver gas diffusion electrode (GDE) or on the CEM—showing that a porous AEL‐coated GDE provides the ...
Henning Lorenz   +3 more
wiley   +1 more source

Light‐Induced Structural Reorganization of Fe Centers Unlocks High Efficiency of Visible‐Light Photo‐Fenton Water Cleaning Catalyst

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Bimetallic Cu and Fe oxide species supported on porous silica with interparticle mesoporosity act as efficient photo‐Fenton‐like catalysts under visible light. Photogenerated electrons drive the Cu2+/Cu1+ redox cycle. Part of Cu1+ is responsible for the regeneration of the Fe3+/Fe2+ cycle at neutral pH. Light irradiation additionally induces structural
Andraž Šuligoj   +6 more
wiley   +1 more source

Local pH Effects on the Temperature Dependence of Product Formation in CO<sub>2</sub> Electrolyzers. [PDF]

open access: yesJ Am Chem Soc
Brandão VD   +8 more
europepmc   +1 more source

Bidentate‐Ligand Molecular Bridge in NiFe‐LDH as a Dynamic Proton Relay and Electronic Modulator to Enhance the Oxygen Evolution Reaction

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
By introducing 4‐chlorobenzoic acid ligands into the interlayer of NiFe‐LDH, the carboxyl and Cl groups on either side are respectively bonded to nearby Fe atoms, yielding a stable Bridge‐Linked structure. The strong electron interaction between the ligands and metal ions suppresses metal ion leaching during the reaction process, thereby maintaining ...
Zhe Sun   +7 more
wiley   +1 more source

Defective CeO2/Copper Phthalocyanine S‐Scheme Heterojunctions With Molecular Copper Centers for Selective CO2‐To‐CO Photoconversion

open access: yesElectron, EarlyView.
Defective CeO2/CuPc S‐scheme heterojunction featuring oxygen‐vacancy‐rich ceria nanorods and atomically dispersed Cu–N4 molecular centers. Built‐in electric field mediates efficient S‐scheme charge separation, accumulating strongly reductive electrons at copper sites for selective CO2‐to‐CO photoconversion (92.2% selectivity) via *COOH stabilization ...
Sharafat Ali   +12 more
wiley   +1 more source

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