Results 91 to 100 of about 48,994 (294)
Advanced Functional Materials, EarlyView.A previously unreported coordination motif stabilising single Fe atoms by indigo chelation and pyridyl coordination on Au(111) has been revealed. By using planar tritopic pyridyl linkers (TPyB), extended 2D porous networks of indigo3(TPyB)2Fe6 form. These networks can be crystalline or vitreous and offer an environment where individual coordination ...
Hongxiang Xu +9 more
wiley +1 more source
Acceleration of Nucleophilic CH Activation by Strongly Basic Solvents [PDF]
, 2010 (IPI)Ru(II)(OH)_n(H_2O)_m, 2, where IPI is the NNN-pincer ligand, 2,6-diimidizoylpyridine, is shown to catalyze H/D exchange between hydrocarbons and strongly basic solvents at higher rates than in the case of the solvent alone.
Goddard, William A., III +4 more
core +1 more source
Directed assembly via selectively positioned host functionality [PDF]
, 2013 Introduction of distal carboxylic acid groups over two positions at the upper-rim of a di-O-alkylcalix[4]arene provides facile control over coordination polymer or discrete metal-organic capsule formation.
Beavers, Christine M +3 more
core +1 more source
Advanced Functional Materials, EarlyView.Bio‐based and (semi‐)synthetic zwitterion‐modified novel materials and fully synthetic next‐generation alternatives show the importance of material design for different biomedical applications. The zwitterionic character affects the physiochemical behavior of the material and deepens the understanding of chemical interaction mechanisms within the ...
Theresa M. Lutz +3 more
wiley +1 more source
Unravelling the surface chemistry of metal oxide nanocrystals, the role of acids and bases [PDF]
, 2014 We synthesized HfO2 nanocrystals from HfCl4 using a surfactant-free solvothermal process in benzyl alcohol and found that the resulting nanocrystals could be transferred to nonpolar media using a mixture of carboxylic acids and amines.
De Keukeleere, Katrien +5 more
core +1 more source
Advanced Functional Materials, EarlyView.This review systematically highlights the latest achievements in mixed‐valence states relevant to hydrogen and oxygen evolution reactions, providing essential insights into future directions and methods for large‐scale practical implementation. This critical review is expected to provide an overview of recent advancements in diverse valence‐state metal
Jitendra N. Tiwari +4 more
wiley +1 more source
Trapping and Characterization of the Reaction Intermediate in Cyclodextrin Glycosyltransferase by Use of Activated Substrates and a Mutant Enzyme [PDF]
, 1997 Cyclodextrin glycosyltransferases (CGTases) catalyze the degradation of starch into linear or cyclic oligosaccharides via a glycosyl transfer reaction occurring with retention of anomeric configuration.
Dijkstra, Bauke W., +4 more
core +3 more sources
Advanced Functional Materials, EarlyView.Amorphous calcium phosphate (ACP) microparticles with long‐term and thermal stability are prepared with or without collagen using a scalable one‐pot spray‐drying process. Under simulated physiological conditions, they crystallize into biomimetic bone mineral and, when combined with collagen, form extrudable, fibrillar bone‐like 3D constructs.
Camila Bussola Tovani +13 more
wiley +1 more source
Temporal changes in carboxylate content of ryegrass with stepwise change in nutrition [PDF]
A detailed scheme of carboxylate formation and retention by plant tissues as a result of ion uptake and utilization is given. By means of discontinuities in the supply with nutrient ions, carboxylate retention by the tissues of perennial ryegrass was ...
Dijkshoorn, W. +2 more
core +2 more sources
Advanced Functional Materials, EarlyView.High‐energy electron impact in plasma catalysis often causes excessive dissociation of active intermediates, limiting C2+ product selectivity. To address this challenge, a bio‐inspired stoma‐shell nanoarchitecture is designed to decouple electron impact from catalytic reaction zones.
Nan Zou +5 more
wiley +1 more source