Results 211 to 220 of about 111,338 (264)

Catalytic 1,2-Radical Acyloxy Migration: A Strategy to Access Novel Chemical Space and Reaction Profiles. [PDF]

Acc Chem Res
Zhao G, Mukherjee U, Yao W, Ngai MY.
europepmc   +1 more source

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Selective short-chain carboxylates production: A review of control mechanisms to direct mixed culture fermentations

Critical Reviews in Environmental Science and Technology, 2016
D Arslan, Hubertus V M Hamelers, H De Wever   +2 more
exaly   +2 more sources

Electrophotocatalytic perfluoroalkylation by LMCT excitation of Ag(II) perfluoroalkyl carboxylates

Science, 2023
Molecular Ag(II) complexes are superoxidizing photoredox catalysts capable of generating radicals from redox-reticent substrates. In this work, we exploited the electrophilicity of Ag(II) centers in [Ag(bpy)2(TFA)][OTf] and Ag(bpy)(TFA)2 (bpy, 2,2 ...
Brandon M. Campbell, Jesse B. Gordon, E. Raguram, Miguel I. Gonzalez, Kristopher G. Reynolds, Matthew Nava, D. G. Nocera   +6 more
semanticscholar   +1 more source

Biological production of medium-chain carboxylates through chain elongation: An overview.

Biotechnology Advances, 2021
Medium chain carboxylates (MCCs) have wide applications in various industries, but the traditional MCCs production methods are costly and unsustainable.
Jianlong Wang, Yanan Yin
semanticscholar   +1 more source

Expanding Reaction Profile of Allyl Carboxylates via 1,2-Radical Migration (RaM): Visible-Light-Induced Phosphine-Catalyzed 1,3-Carbobromination of Allyl Carboxylates

Journal of the American Chemical Society, 2023
Allyl carboxylates are useful synthetic intermediates in a variety of organic transformations, including catalytic nucleophilic/electrophilic allylic substitution reactions and 1,2-difunctionalization reactions. Yet, the catalytic 1,3-difunctionalization
Gaoyuan Zhao, S. Lim, D. Musaev, Ming-Yu Ngai   +3 more
semanticscholar   +1 more source

Selectively upgrading lignin derivatives into carboxylates through electrochemical oxidative C(OH)-C bonds cleavage by a Mn-doped cobalt oxyhydroxide catalyst.

Angewandte Chemie, 2021
Oxidative cleavage of C(OH)-C bonds to afford carboxylates is of significant importance for petrochemical industry and biomass valorization. Here we report an efficient electrochemical strategy for selective upgrading of lignin derivatives into ...
Hua Zhou, Zhenhua Li, Si-Min Xu, Lilin Lu, Minggui Xu, Kaiyue Ji, Ruixiang Ge, Yifan Yan, Lina Ma, X. Kong, Lirong Zheng, Haohong Duan   +11 more
semanticscholar   +1 more source

Silicon mobilisation by root-released carboxylates.

Trends in Plant Science, 2021
Plants have evolved numerous strategies to acquire poorly available nutrients from soil, including the release of carboxylates from their roots. Silicon (Si) release from mineral dissolution increases in the presence of chelating substances, and recent ...
F. de Tombeur, J. Cornelis, H. Lambers
semanticscholar   +1 more source

Superfast and Water-Insensitive Polymerization on α-Amino Acid N-Carboxyanhydrides to Prepare Polypeptides using Tetraalkylammonium carboxylates as the Initiator.

Angewandte Chemie, 2021
Proteins and peptides have diverse biological functions and applications, however, their efficient chemical synthesis is still challenging.
Yueming Wu, Kang Chen, Xue Wu, Longqiang Liu, Weiwei Zhang, Yun Ding, Shiqi Liu, Min Zhou, Ning Shao, Zhemin Ji, Jiacheng Chen, Minghui Zhu, Runhui Liu   +12 more
semanticscholar   +1 more source

Palladium-Catalyzed Cross-Coupling of Alkenyl Carboxylates.

Angewandte Chemie, 2020
Carboxylate esters have many desirable features as electrophiles for catalytic cross-coupling: they are easy to access, robust during multistep synthesis, and mass efficient in coupling reactions.
Joseph Becica, Oliver R. J. Heath, Cameron H. M. Zheng, D. Leitch   +3 more
semanticscholar   +1 more source

Characterisation of metal carboxylates by Raman and infrared spectroscopy in works of art

Journal of Raman Spectroscopy, 2014
Vanessa Otero, Cristina Montagner, Marcia Vilarigues   +2 more
exaly   +2 more sources