Catalytic enantioselective addition of organometallics to unprotected carboxylic acids
Nature Communications, 2019 Unprotected carboxylic acids are classically deemed to be unsusceptible to conjugated additions due to acid-base neutralization. Here, the authors show that the use of an appropriate Lewis acid allows the catalytic addition of organometallics to ...
Xingchen Yan, Syuzanna R. Harutyunyan
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Cooperative catalysis by silica-supported organic functional groups [PDF]
, 2008 Hybrid inorganic–organic materials comprising organic functional groups tethered from silica surfaces are versatile, heterogeneous catalysts. Recent advances have led to the preparation of silica materials containing multiple, different functional groups
Davis, Mark E. +2 more
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A copper(II) complex with neutral carboxylic acid ligand [PDF]
, 2011 Hiroshi Miyamae, Kaguya Ito, G. Hihara
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In Situ 3D Bioprinting: Impact of Cross‐Linking on the Adhesive Properties of Hydrogels
Advanced Functional Materials, EarlyView.In situ 3D bioprinting enables the direct deposition of cell‐laden, adhesive biomaterials for on‐site tissue regeneration. This review provides a comprehensive overview of how cross‐linking influences the bioadhesive properties of hydrogels used in 3D bioprinting, highlighting cross‐linking triggers, bioadhesion mechanisms, polymer interpenetration ...
Odile Romero Fernandez +4 more
wiley +1 more source
α-pinene photooxidation under controlled chemical conditions – Part 2: SOA yield and composition in low- and high-NO_x environments [PDF]
, 2012 The gas-phase oxidation of α-pinene produces a large amount of secondary organic aerosol (SOA) in the atmosphere. A number of carboxylic acids, organosulfates and nitrooxy organosulfates associated with α-pinene have been found in field samples and some ...
Chan, M. +7 more
core
Study on differential expression of 1-aminocyclopropane-1-carboxylic acid oxidase genes in table grape cv. Thompson Seedless [PDF]
, 2013 As a consequence of the non-climacteric status of grapes (Vitis vinifera), ethylene biosynthesis and signal transduction have scarcely been studied in this fruit.
Campos-Vargas, Reinaldo +5 more
core +3 more sources
Effects of Molecular Designs and Double‐Network Morphologies for Bioadhesive Semiconductors
Advanced Functional Materials, EarlyView.This study establishes molecular‐to‐mesoscale design rules for bioadhesive semiconducting polymers (BASCs). It identifies how side‐chain length, double‐network formation, and film thickness modulate adhesion strength and electronic performance, providing insight into the rational design of intrinsically adhesive semiconductors for stable and efficient ...
Zhichang Liu +8 more
wiley +1 more source
Status of the Reactive Extraction as a Method of Separation
Journal of Chemistry, 2015 The prospective function of a novel energy efficient fermentation technology has been getting great attention in the past fifty years due to the quick raise in petroleum costs.
Dipaloy Datta, Sushil Kumar, Hasan Uslu
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The Partial Reduction of Carboxylic Acids to Aldehydes via 3-Acylthiazolidine-2-thiones with Diisobutylaluminum Hydride and with Lithium Tri-t-butoxyaluminum Hydride [PDF]
, 1979 Toshio Izawa, Teruaki Mukaiyama
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Adaptive Hydrogels With Spatiotemporal Stiffening Using pH‐Modulating Enzymes
Advanced Functional Materials, EarlyView.The chemomechanical coupling in an adaptive hydrogel is studied to further the development of adaptive hydrogels. This coupling is achieved by embedding a pH‐modulating enzyme in a pH‐responsive hydrogel. The enzymatic reaction can be triggered locally, which generates a pH‐decreasing wave throughout the system, increasing the crosslinking density and ...
Natascha Gray +3 more
wiley +1 more source