Results 21 to 30 of about 1,209 (116)

Proline‐Derived N‐Heterocyclic Carbene Gold(I) Complexes With Dual DNA Binding and Thioredoxin Reductase Inhibition

open access: yesChemMedChem, Volume 21, Issue 16, 27 August 2026.
Proline‐derived Au(I)–NHC complexes display potent anticancer activity against lung and triple‐negative breast cancer cells. The cationic complexes promote DNA intercalation, thioredoxin reductase inhibition, ROS overproduction, and mitochondrial membrane depolarization, ultimately triggering apoptotic cell death through a multimodal mechanism of ...
Giacomo Cassarà   +3 more
wiley   +1 more source

Magnetita (Fe3O4): Una estructura inorgánica con múltiples aplicaciones en catálisis heterogénea

open access: yesRevista Colombiana de Química, 2017
Se describió la intervención del mineral magnetita como catalizador o como soporte catalítico, un material inorgánico con una estructura de espinela inversa (FeFe2O4), en el desarrollo de un número importante de reacciones químicas de interés científico,
José Gregorio Carriazo Baños   +2 more
doaj   +1 more source

Catalytic Deuteration of Amines in Water (D2O) With Ir, Ru, and Rh Pentamethylcyclopentadienyl Dioxime Complexes

open access: yesChemistryEurope, Volume 4, Issue 8, August 2026.
A new family of pentamethylcyclopentadienyl (C5Me5, Cp*) iridium(III), rhodium(III), and ruthenium(III) complexes bearing bidentate 1,2‐dioxime ligands was developed and their catalytic performances were evaluated in the hydrogen‐borrowing‐type H/D exchange of amines using D2O as both solvent and deuterium source. Iridium derivatives achieved excellent
Francesco Taglieri   +8 more
wiley   +1 more source

Polyesterase activity and thermostability of carboxylesterases from Thermoleophilum album YS‐3

open access: yesThe FEBS Journal, Volume 293, Issue 15, Page 4724-4743, August 2026.
Three novel α/β‐hydrolases from thermophilic bacterium Thermoleophilum album display carboxylesterase and polyesterase activity. These enzymes hydrolyse PET, PLA and PCL both at high and moderate temperatures. TA21 shows superior activity, efficiently converting MHET to terephthalic acid. Structural features underlying substrate binding highlight their
Tatyana N. Chernikova   +6 more
wiley   +1 more source

Iniciativas institucionales e individuales en la creación de estructuras científicas: El Instituto de Tecnología Química

open access: yesArbor: Ciencia, Pensamiento y Cultura, 2007
Se analiza la evolución del Instituto de Tecnología Química (ITQ), centro mixto del Consejo Superior de Investigaciones Científicas y de la Universidad Politécnica de Valencia, desde su creación en 1990 en el marco de una iniciativa de colaboración ...
Elena Castro Martínez   +1 more
doaj   +1 more source

Investigation of Substrate Specificity in 5‐Keto‐4‐Deoxy‐Glucarate Dehydratase and 2‐Keto‐3‐Deoxy‐L‐Arabinonate Dehydratase

open access: yesChemBioChem, Volume 27, Issue 14, 29 July 2026.
5‐Keto‐4‐deoxy glucarate dehydratase and 2‐keto‐3‐deoxy‐L‐arabinonate dehydratase share many similarities like structure, reaction mechanism, and their generated product, but exhibit very high substrate specificity. Here, we explore the evolutionary development of this specificity in the context of the enzyme superfamily and attempt to find promiscuous
Kathrin Hörnschemeyer   +4 more
wiley   +1 more source

Nicolas Clément

open access: yesEducación Química, 2018
Nicolás Clément (1779-1841) fue un brillante científico e industrial, aun cuando no tuvo una educación formal. Solo, o en colaboración con su suegro, Bernard Desormes, desarrolló la teoría de la fabricación del ácido sulfúrico por el método de las ...
Jaime Wisniak
doaj   +1 more source

Electrochemical studies of galactose oxidase

open access: yesElectrochemical Science Advances, 2022
One of the most interesting redox biocatalysts is galactose oxidase, a redox enzyme that catalyzes the oxidation of d‐galactose to 1,6‐d‐galactodialdose in a single copper redox site.
Carina Figueiredo   +2 more
doaj   +1 more source

La mancha indeleble de Aniceto Hevia: determinismo y superación en la tetralogía narrativa de Manuel Rojas

open access: yesLiteratura: Teoría, Historia, Crítica, 2015
El presente artículo propone un estudio de las catálisis o detalles de la narración en la tetralogía narrativa de Manuel Rojas, es decir, Hijo de ladrón (1951), Mejor que el vino (1958), Sombras contra el muro (1964) y La oscura vida radiante (1971).
Pablo Fuentes Retamal
doaj   +1 more source

Novel enzyme-polymer conjugates for biotechnological applications [PDF]

open access: yesPeerJ, 2013
In the present research, a rapid, simple and efficient chemoselective method for the site-directed incorporation of tailor-made polymers into protein to create biocatalysts with excellent properties for pharmaceutical industrial purpose has been ...
Oscar Romero   +3 more
doaj   +2 more sources

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