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Homogeneous catalysts to solid catalysts
Current Opinion in Solid State and Materials Science, 1996Abstract Recent advances have been made in the transformation of homogeneous to solid catalysts. They include the use of metal complexes immobilized on organic and inorganic supports, solid acids and bases, redox molecular sieves as solid catalysts for liquid phase oxidations, zeolite-encapsulated metal complexes and supported liquid phase catalysts.
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Angewandte Chemie, 2019
Atomically dispersed Zn-N-C nanomaterials are promising platinum-free catalysts for the oxygen reduction reaction (ORR). However, the fabrication of Zn-N-C catalysts with a high Zn loading remains a formidable challenge owing to the high volatility of ...
Jia Li +8 more
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Atomically dispersed Zn-N-C nanomaterials are promising platinum-free catalysts for the oxygen reduction reaction (ORR). However, the fabrication of Zn-N-C catalysts with a high Zn loading remains a formidable challenge owing to the high volatility of ...
Jia Li +8 more
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Highly Efficient and Selective Generation of Ammonia and Hydrogen on a Graphdiyne-Based Catalyst.
Journal of the American Chemical Society, 2019The emergence of zerovalent atom catalysts has been highly attractive for catalytic science. For many years, scientists have explored the stability of zerovalent atom catalysts and demonstrated their unique properties. Here, we describe an atom catalyst (
Lan Hui +7 more
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Metal-Free Single Atom Catalyst for N2 Fixation Driven by Visible Light.
Journal of the American Chemical Society, 2018Solar nitrogen (N2) fixation is the most attractive way for the sustainable production of ammonia (NH3), but the development of a highly active, long-term stable and low-cost catalyst remains a great challenge.
Chongyi Ling +4 more
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Advances in Materials, 2018
The discovery of stable and noble‐metal‐free catalysts toward efficient electrochemical reduction of nitrogen (N2) to ammonia (NH3) is highly desired and significantly critical for the earth nitrogen cycle.
Ling Zhang +9 more
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The discovery of stable and noble‐metal‐free catalysts toward efficient electrochemical reduction of nitrogen (N2) to ammonia (NH3) is highly desired and significantly critical for the earth nitrogen cycle.
Ling Zhang +9 more
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Chemical Society Reviews, 2020
The urgent need to address the high-cost issue of proton-exchange membrane fuel cell (PEMFC) technologies, particularly for transportation applications, drives the development of simultaneously highly active and durable platinum group metal-free (PGM ...
Yanghua He +4 more
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The urgent need to address the high-cost issue of proton-exchange membrane fuel cell (PEMFC) technologies, particularly for transportation applications, drives the development of simultaneously highly active and durable platinum group metal-free (PGM ...
Yanghua He +4 more
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Microkinetic Modeling: A Tool for Rational Catalyst Design.
Chemical Reviews, 2020The design of heterogeneous catalysts relies on understanding the fundamental surface kinetics that controls catalyst performance, and microkinetic modeling is a tool that can help the researcher in streamlining the process of catalyst design ...
A. H. Motagamwala, J. Dumesic
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Unifying views on catalyst deactivation
Nature Catalysis, 2022A. Martín +4 more
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Induced activation of the commercial Cu/ZnO/Al2O3 catalyst for the steam reforming of methanol
Nature Catalysis, 2022Didi Li +10 more
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2011
A solid particulate catalyst free from an external carrier comprising (i) a complex of Formula (I), wherein M is zirconium or hafnium; each X is a sigma ligand; L is a divalent bridge selected from -R'2C-, -R'2C-CR'2-, -R'2Si-, -R'2Si-SiR2-, -R'2Ge-, wherein each R' is independently a hydrogen atom, Cl-C20-alkyl, tri(C1-C20-alkyl)silyl, C6-C20-aryl, C7-
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A solid particulate catalyst free from an external carrier comprising (i) a complex of Formula (I), wherein M is zirconium or hafnium; each X is a sigma ligand; L is a divalent bridge selected from -R'2C-, -R'2C-CR'2-, -R'2Si-, -R'2Si-SiR2-, -R'2Ge-, wherein each R' is independently a hydrogen atom, Cl-C20-alkyl, tri(C1-C20-alkyl)silyl, C6-C20-aryl, C7-
BOREALIS AG +3 more
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