Results 171 to 180 of about 116,945 (219)

Active Phase of Nickel Electrocatalysts Driving Alkaline Hydrogen Evolution

Advanced Materials, EarlyView.
Using depth‐resolved and operando spectroscopic measurements coupled with electrochemical mass spectrometry, the authors uncover the critical role of sub‐surface oxidised species in increasing the activity and durability of Ni‐based cathodes for hydrogen evolution.
Yifeng Wang, Eleanor Ender, Santosh Kumar, Cindy Tseng, Guangmeimei Yang, Boxi Ye, Caiwu Liang, Youli Yu, Norton West, Inderjeet Chauhan, Jun H. Ng, Sid Halder, Sang Gu Ji, Georg Held, Mary P. Ryan, Katie L. Moore, Alex S. Walton, Reshma R. Rao   +17 more
wiley   +1 more source

Using Classifiers To Predict Catalyst Design for Polyketone Microstructure. [PDF]

J Am Chem Soc
Wong YP, Jung HJ, Lin S, Shammami MA, Roshandel H, Dodge HM, Chapp SM, Ruiz De Castilla LC, Wang D, Do LH, Liu C, Miller AJM, Diaconescu PL.   +12 more
europepmc   +1 more source

Review of Inorganic Separator Engineering for Next‐Generation Lithium–Sulfur Batteries: Compromise or Cornerstone?

Advanced Materials, EarlyView.
Inorganic compound‐modified separators transform lithium–sulfur batteries from passive polysulfide confinement to active reaction‐pathway regulation. A Practical Relevance Index (PRI)‐guided framework bridges interfacial chemistry of inorganic separators with practical constraints, establishing unified design principles for scalable, high‐energy ...
Yuting Qin, Tianyi Wang, Xingyu Wang, Kaifu Xu, Yuzhou Wang, Chengyin Wang, Bing Sun, Guoxiu Wang   +7 more
wiley   +1 more source

Colloidal Templating in Catalyst Design for Thermocatalysis. [PDF]

J Am Chem Soc
Lim KRG, Aizenberg M, Aizenberg J.
europepmc   +1 more source

S‐Nitrosothiols as Thiol‐Protecting Groups for Controlled Thiol‐Maleimide Crosslinking of Homogeneous Soft Hydrogels

Advanced Materials, EarlyView.
Rapid thiol‐maleimide addition frequently outpaces mixing, resulting in heterogeneous hydrogels. S‐nitrosothiols act as thiol‐protecting groups, allowing uniform mixing with maleimide‐functionalized polymers before gelation. Sodium thiosulfate or sodium ascorbate then regenerates thiols on demand, triggering controlled thiol‐maleimide crosslinking ...
Julian A. Serna, Michelle J. Iwohn, Maximilian Seifermann, Stefan Heißler, Maike Schliephake, Franziska Dopp, Claudia Muhle‐Goll, Pavel A. Levkin   +7 more
wiley   +1 more source

Advances in Catalyst Design for β-Lactone Formation via Ring-Expansion Carbonylation. [PDF]

Molecules
Hasnain A, Ganesan V, Yoon S.
europepmc   +1 more source

Sub‐Nanometer Cobalt on Tungsten Titanium Carbide MXene (W2TiC2Tx): An Electrocatalyst for Highly Efficient and Stable Alkaline Hydrogen Evolution at Industrial‐Scale Current Density

Advanced Materials, EarlyView.
A novel W2TiC2Tx MXene prepared through a MAX‐phase route supports sub‐nanometer Co for highly efficient alkaline hydrogen evolution. Strong Co–W interfacial interactions optimize hydrogen adsorption and catalytic activity, enabling low overpotentials of 63 mV at 10 mA cm−2, small Tafel slope of 44.3 mV dec−1, and exceptional durability at industrially
Xiaopeng Liu, Fan Yang, Deep M. Patel, Mohammad Albloushi, Qiqi Mao, Shan Jiang, Christian J. Breckner, Connor W. Schroeder, Ruoyu Cui, Tao Ma, Dapeng Jing, Wenyu Huang, Jeffrey T. Miller, Wenzhen Li, Luke T. Roling, Yue Wu   +15 more
wiley   +1 more source

Electrosynthesis of Hydrogen Peroxide at Industrial-Level Current Density in Flow-Cell System: Interfacial Microenvironment Regulation and Catalyst Design. [PDF]

Small Sci
Albashir AIM, Li Y, Dou J, Qi K, Qi W.
europepmc   +1 more source

Efficient Hydroxyl Diffusion Triggers Surface Hydronium Enrichment and Bulk Proton Participation to Boost Alkaline Hydrogen‐Evolving Reaction

Advanced Materials, EarlyView.
For the first time, we shed light on the surface‐to‐bulk diffusion, induction, and reaction behaviors of OH−, H+, and H2O species on model oxides for alkaline hydrogen‐evolving reaction (HER). We first demonstrate that bulk OH− diffusion significantly affects the generation of proton sources and the diffusion/reaction behaviors of protons, thus ...
Daqin Guan, Hengyue Xu, Xiao Sun, Leqi Zhao, Chun‐Kuo Peng, Chao Jing, Yu‐Cheng Huang, Jiayi Tang, Nai Shi, Zezhou Lin, Xiaomin Xu, Zhiwei Hu, Zongping Shao   +12 more
wiley   +1 more source

Mechanistic Organometallic Studies Drive Reagent Selection and Catalyst Design for the Palladium-Catalyzed Trifluoromethylthiolation of Aryl Electrophiles. [PDF]

Organometallics
Thedford J, Sanford MS.
europepmc   +1 more source