Electron‐Deficient Linkers Enhance H2O2 Electrosynthesis in Covalent Organic Frameworks
Linker π‐conjugation modulates the electronic state of the Ni–N4 centers and their interaction with the key *OOH intermediate while preserving the primary coordination motif. NiPc‐PTDA delivers an H2O2 selectivity of 92% and a production rate of 34.8 mol gcat−1 h−1, highlighting linker electronic properties as a molecular design parameter for NiPc ...
Houting Xie +7 more
wiley +1 more source
Synthesis of a Mesoporous SnO2 Catalyst Support and the Effect of Its Pore Size on the Performance of Polymer Electrolyte Fuel Cells. [PDF]
Inaba M +11 more
europepmc +1 more source
Polyethyleneimine-Modified Polymer as an Efficient Palladium Scavenger and Effective Catalyst Support for a Functional Heterogeneous Palladium Catalyst. [PDF]
Yamada T +11 more
europepmc +1 more source
Architecture‐Driven Functional Coupling in Vertically Aligned Nanocomposites
Vertically aligned nanocomposites define a growth‐engineered architecture in which vertical interfaces, strain fields, defect pathways, and phase connectivity are created simultaneously. This review shows how these architectural features couple ferroic, optical, ionic, electrochemical, and device responses, establishing design rules and open challenges
Md Shatil Islam‐Shanto +4 more
wiley +1 more source
Engineering catalyst-support interactions in cobalt phthalocyanine for enhanced electrocatalytic CO<sub>2</sub> reduction: the role of graphene-skinned Al<sub>2</sub>O<sub>3</sub>. [PDF]
Bai Q +15 more
europepmc +1 more source
An anode catalyst support for polymer electrolyte membrane fuel cells: application of organically modified titanium and silicon dioxide. [PDF]
Malinowski M +3 more
europepmc +1 more source
We investigate size‐dependent CO selectivity on Ag nanoparticles, where optimized Ag loading achieves nearly 100% Faradaic Efficiency for CO at −100 mA·cm−2. In situ SERS and XPS reveal the crucial role of optimized loading in catalytic performance. The Ag/C catalyst further exhibits bifunctional activity, enabling efficient electrolysis of CO2 and ...
Venkata S. R. K. Tandava +16 more
wiley +1 more source
Inspired by metal‐free carbonic anhydrases (CAs) that achieve efficient catalysis without metal cofactors, we herein report a sequence‐defined supramolecular peptoid platform that mimics metal‐free CAs and exhibits hydrolytic activity via a supramolecular assembly‐mediated proton‐transfer mechanism.
Progyateg Chakma +8 more
wiley +1 more source
Graphitized Carbon: A Promising Stable Cathode Catalyst Support Material for Long Term PEMFC Applications. [PDF]
Mohanta PK, Regnet F, Jörissen L.
europepmc +1 more source
Top‐down ultrasonication produces highly emissive Cs2ZrCl6:Te4+ nanocrystals (NCs) with a PLQY of 65%, which is higher compared to that of the NCs synthesized by typical bottom‐up hot‐injection synthesis. The colloidal Cs2ZrCl6:Te4+ NCs have been found to be potential candidates for x‐ray scintillation imaging.
Yang Liu +12 more
wiley +1 more source

