Results 151 to 160 of about 58,988 (308)

Steering Oxygen Activation Pathways via Redox Dual‐Defects in 2D Hydrated WO3 for High‐Yield Singlet Oxygen Evolution

open access: yesAdvanced Functional Materials, EarlyView.
Redox dual‐defects (Cs substitution and O vacancies) in 2D hydrated WO3 steer O2 activation toward selective singlet oxygen evolution. WO‐CO achieves 8.6–15.8 times higher 1O2 production than single‐defect or pristine catalysts, enabling efficient pollutant mineralization via a pathway‐selective photocatalytic mechanism.
Sheng‐Qi Guo   +8 more
wiley   +1 more source

Is It Real Type‐II or S‐Scheme? A Three‐Phase Diagnostic Protocol for Identifying Potentially Mislabeled Heterojunction Photocatalysts

open access: yesAdvanced Functional Materials, EarlyView.
Diagnostic analysis via the heterojunction validation funnel. The funnel illustrates the hierarchical stratification of 30 reported Type‐II systems based on the three‐phase, seven‐step diagnostic framework. Complete validation through all phases is achieved by only 3.3% of systems, while 96.7% lack full mechanistic validation, revealing a pervasive ...
Ki‐Hyun Kim
wiley   +1 more source

Myrcene‐Based Tailored Co‐Polymers as Active Pharmaceutical Excipients: Bio‐Based Solutions for Mucoadhesive Excipients

open access: yesAdvanced Functional Materials, EarlyView.
Mucoadhesive amphiphilic block and statistical copolymers were synthesized via Reversible Addition–Fragmentation Chain Transfer polymerization from bio‐sourced myrcene and polyethylene glycol methacrylate. The resulting polymers exhibit narrow molar‐mass distributions, high regioselectivity, well‐defined microstructures, and tend to self‐assemble into ...
David Gintsburg   +9 more
wiley   +1 more source

An investigation into coking on catalyst support materials & supported metal catalysts

open access: yes, 1997
The deposition of coke on oxidation catalysts leads to deactivation. For oxide supports this phenomena of coking has previously been identified with acidic sites. Measurement of coke formation on silica gel, a-, r|- and y-Al2 0 3 showed that the greatest amount of coke was formed on y-A12 0 3 followed by r(-Al2 0 3 with no detectable coking occurring ...
openaire   +1 more source

Engineering MnNiPx Cathode via Dual Role of Mn: Simultaneous Enhancement of Activity and Intermittent Operation Durability

open access: yesAdvanced Functional Materials, EarlyView.
Engineering MnNiPx cathodes through the dual role of Mn simultaneously improves hydrogen evolution reaction activity and intermittent‐operation durability. Mn preferentially oxidizes to protect Ni–P sites from irreversible oxidation, while metallic Mn incorporation enhances the HER kinetics of Ni–P active layer.
Ik‐Sun Kim   +16 more
wiley   +1 more source

Taming the stability of Pd active phases through a compartmentalizing strategy toward nanostructured catalyst supports. [PDF]

open access: yesNat Commun, 2019
Yang X   +11 more
europepmc   +1 more source

Coupling Anodic Activity and Stability at Ni‐Based Non‐Oxide Catalysts via Coordinating Alcohol Oxidation and Oxygen Evolution

open access: yesAdvanced Functional Materials, EarlyView.
A cooperative and competitive interrelationship between alcohol oxidation (AOR) and water oxidation (OER) was observed on a typical anode catalyst of Ni2P. In situ Raman spectroscopy and electrochemical analyses revealed a specific complementary mechanism between them, in which OER and AOR critically contribute to the activity and stability of anodic ...
Yong Yan   +10 more
wiley   +1 more source

Reduced Graphene Oxide and Its Modifications as Catalyst Supports and Catalyst Layer Modifiers for PEMFC. [PDF]

open access: yesMaterials (Basel), 2018
Grigoriev SA   +7 more
europepmc   +1 more source

Support‐Controlled Reaction Pathways via Dynamic Sulfur‐Mediated Interfaces for Selective Urea Electrolysis

open access: yesAdvanced Functional Materials, EarlyView.
Sulfur‐doped graphitized carbon nanofibers act as adaptive catalyst–support platforms, enabling dynamic sulfur‐mediated reconstruction and strong metal–support interactions. This unique behavior enhances catalyst stability and controls reaction pathways, achieving highly selective urea oxidation (∼92% N2) coupled with efficient hydrogen evolution ...
Melanie Guillén‐Soler   +4 more
wiley   +1 more source

Metal-Organic Frameworks as Catalyst Supports: Influence of Lattice Disorder on Metal Nanoparticle Formation. [PDF]

open access: yesChemistry, 2018
Rivera-Torrente M   +11 more
europepmc   +1 more source

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