Results 101 to 110 of about 53,863 (261)
Hydrogenolysis of Guaiacol to Phenol Over Ru‐FeOx Nanoparticles Supported on TiO2
This work demonstrates that the Ru/FeOx–TiO2 catalyst enables selective CAr–OCH3 bond cleavage in water, achieving a phenol selectivity of 81.1% at a 90.4% conversion of guaiacol. The synergy between Ru and FeOx can effectively promote the selective hydrogenolysis of CAr–OCH3 bonds without the obvious hydrogenation of the benzene ring.
Jingping Wang +9 more
wiley +1 more source
Structural engineering of conjugated conductive polymer binders enables integrated electronic transport, strong adhesion, and stable electrode interfaces, offering a promising strategy to reduce inactive components and improve the performance of high‐energy lithium batteries.
Fating Wang +7 more
wiley +1 more source
A Mononuclear Scenario for the Copper‐Catalyzed Monooxygenation of Phenolic Substrates
ABSTRACT Whereas a dinuclear pathway applies to the monooxygenation of phenols by the type 3 copper enzyme tyrosinase, a mononuclear pathway has been identified for the same reaction in corresponding small‐molecule systems. DFT calculations of five copper model complexes reveal that the latter mechanism is energetically feasible, identifying all ...
Alexander Koch +3 more
wiley +1 more source
Abstract Objectives Central poststroke pain (CPSP), a neuropathic pain condition, is difficult to treat. Repetitive transcranial magnetic stimulation (rTMS) targeted to the primary motor cortex (M1) can alleviate the condition, but not all patients respond. We aimed to assess a promising alternative rTMS target, the secondary somatosensory cortex (S2),
Juhani Ojala +10 more
wiley +1 more source
Lighting up the path to precision oncology: This review comprehensively summarizes the rational design of carbon dots (CDs), elucidating how core size, surface chemistry, and heteroatom doping dictate their luminescence mechanisms. Special emphasis is placed on engineering NIR‐II emissive CDs for deep‐tissue imaging.
Zekun Yan +3 more
wiley +1 more source
The catechol amines and their receptors.
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openaire +3 more sources
A series of thirteen (N‐heterocyclic carbene) NHC‐stabilized borenium cations is synthesized from NHC→BH3 complexes via hydroboration and condensation with diols. The novel compounds are fully characterized. Eight crystal structures are presented. Kinetic and NMR data show how the structural features translate to catalytic activity in hydrosilylation ...
Michał Jakubczyk +4 more
wiley +1 more source
Bioinspired Design and Synthesis of Polyphenolic Star‐Like and Hyperbranched Polyester Models
Gallotannin‐inspired star‐like and hyperbranched aromatic polyesters were synthesized from D‐glucose and ABn‐type phenolic acid monomers, such as protocatechuic acid. This bioinspired approach afforded polyphenolic polymeric nanoparticles able to encapsulate hydrophobic dyes, opening new perspectives for biobased encapsulation and delivery systems ...
Guanfei Shen +4 more
wiley +1 more source
Hybrid macrocyclic peptides unite genetically encoded peptide libraries with the structural complexity of synthetic small molecules. This Review critically analyzes phage‐compatible cyclization and diversification chemistries, highlights emerging opportunities beyond traditional cysteine‐based approaches, and outlines how future advances may enable the
Titia Rixt Oppewal, Clemens Mayer
wiley +1 more source
In this work, a novel biomolecule/semiconductor hybrid catalyst was prepared by loading anthraquinone‐liked juglone onto anatase TiO2. This catalyst exhibited high photocatalytic activity for H2O2 production. Hydrogen peroxide (H2O2) is a vital oxidant with broad industrial applications, and its production via photocatalysis represents a highly ...
Zengyin He +4 more
wiley +1 more source

