Results 181 to 190 of about 163,771 (279)

Separating Hydrogen Evolution From Electroplating in Zn Metal Batteries Using Scanning Electrochemical Microscopy

open access: yesAdvanced Energy Materials, EarlyView.
Operando SECM decouples hydrogen evolution from other degradation pathways in Zn metal batteries by quantifying its contribution during Zn electrodeposition. Although HER is shown to account for only a minor fraction of the irreversible charge loss, it remains a key indicator of interfacial evolution and by‐product formation governing cycling ...
J. T. Simon   +8 more
wiley   +1 more source

A Fluorine‐Free, Low Ion Pair Electrolyte for Transition Metal‐Free and Halogen‐Free Sodium Batteries

open access: yesAdvanced Energy Materials, EarlyView.
Fluorine‐containing electrolytes dominate modern rechargeable batteries, yet the fundamental design principles for fluorine‐free systems remain largely unexplored. We demonstrate that fluorine‐free electrolyte chemistry can simultaneously achieve long cycle life, fast charging, and stable interphase formation in sodium‐ion batteries.
Dawei Xia   +7 more
wiley   +1 more source

Surface‐Engineered Ti3C2Tx MXene/Cu2O Photocathodes for Highly Selective Photoelectrocatalytic CO2 Reduction to Ethanol

open access: yesAdvanced Energy Materials, EarlyView.
Surface‐engineering Ti3C2Tx MXenes with an in situ‐grown TiO2 layer on the surface in combination with visible‐light‐absorbing Cu2O significantly enhances charge separation and carrier extraction while improving Cu2O resistance to photocorrosion. The resulting Cu2O/TiO2‐MXene photocathodes enable highly selective, solar‐driven ethanol production ...
Luis A. M. Carrascosa   +4 more
wiley   +1 more source

Internal Electric Field‐Guided, Low‐Adsorption Ferroelectric Anode Protective Layers for Sustainable Suppression of Polysulfide Side Reactions in Lithium–Sulfur Batteries

open access: yesAdvanced Energy Materials, EarlyView.
A positively polarized ferroelectric β‐pvdf layer incorporating fluorinated boron nitride nanosheets (PPFBN) establishes a strong internal field that promotes Li+ transport toward the anode while suppressing the migration of polysulfide anions. In addition, its intrinsically low polysulfide affinity helps preserve protective‐layer functionality ...
Daehun Han   +6 more
wiley   +1 more source

Mechanistic Origin of Capacity Limitation in Sidorenkite‐Type Na3‐xFe(PO4)(CO3) Carbonophosphate Cathodes for Na‐Ion Batteries

open access: yesAdvanced Energy Materials, EarlyView.
The potential–capacity profile reveals a one‐electron limitation in sidorenkite Na3−xFe(PO4)(CO3). Structural analysis shows that Fe4+ formation induces lattice strain and suppresses electronic conductivity, blocking further Na extraction. These findings establish key design rules: preserve crystallinity, avoid Jahn–Teller–active d4 configurations, and
Samuel Franz Gatti   +7 more
wiley   +1 more source

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