Carboxyphenolate Coordination Frameworks for High‐Voltage Calcium Storage
A hexaanionic carboxyphenolate coordination framework, Ca2‐M‐THBPD (M = Mg, Ca, Ba), exhibits ligand‐centered enolate‐quinonoid redox activity enabling tunable, high‐voltage Ca2+ storage (3.5 V vs Ca2+/Ca) modulated by spectator cations. The amorphous structure accommodates reversible divalent‐ion insertion, contributing to enhanced cycling stability ...
Vasudeva Rao Bakuru +12 more
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Innovative Use of Stone Waste for Sustainable Fertility Management in Tropical Soils. [PDF]
Borges RC +8 more
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This work presents a molecular‐level kinetic regulation strategy employing iodoacetic acid (IAA) to simultaneously suppress point defects and solvent inclusion in solution‐grown Cs4PbI6 single crystals. The obtained crystals demonstrate significantly enhanced charge transport properties, enabling X‐ray detectors with high sensitivity, low noise, and ...
Hui Zhang +9 more
wiley +1 more source
Preparation of K<sub>2</sub>SbPO<sub>6</sub>-Loaded Porous Geopolymer Particles for Efficient Sr(II) Removal: Adsorption Performance and Mechanism. [PDF]
Cheng C, Fang W, Ouyang G, Wang J.
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An atomically dispersed Co–N4 single‐atom catalyst rapidly activates peroxymonosulfate to remove the antibiotic sulfamethoxazole from water. Common ions have little impact, but chloride dramatically speeds degradation by promoting a high‐valent Co(IV) = O oxidant via in situ HOCl–catalyst electron transfer.
Anting Ding +6 more
wiley +1 more source
Principles for Optimal Electrode Design and Operation for Desalination with Electrochemical Ion Pumping. [PDF]
Liu W, Xu L, Lin S.
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The weakly‐solvating TFMSPyr electrolyte tailors the Li+ solvation structure by suppressing solvent coordination and promoting anion‐dominated solvation. This unique solvation environment induces preferential anion decomposition at electrode interfaces, forming robust inorganic rich S/CEI.
Bishnu P. Thapaliya +11 more
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Zeolite-Based Composite Nanomaterials for Organic Micropollutant Removal: Structure-Property-Performance Relationships and Practical Challenges. [PDF]
Aisha N +9 more
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Hydrothermal Humification of Biomass for Circular Carbon Management in Sustainable Agro‐Ecosystems
This article provides a comprehensive overview of biomass hydrothermal humification for building sustainable agro‐ecosystems. It examines the chemical transformation mechanisms and the functional benefits of the produced humic acids in soil remediation.
Ziyun Liu +4 more
wiley +1 more source
Interfacial ion aggregation at SiO<sub>2</sub> nanoparticles enhances thermal energy storage of chloride molten salts: a molecular dynamics study. [PDF]
Wang C, Hu H, Li Q, Guo L, Yang M.
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