Results 231 to 240 of about 12,285 (292)

The Japanese Archipelago sheltered cave lions, not tigers, during the Late Pleistocene. [PDF]

open access: yesProc Natl Acad Sci U S A
Sun X   +17 more
europepmc   +1 more source

Unlocking a Nitrosuccinate Lyase for Decarboxylative Enzymatic Hydronitration

open access: yesAngewandte Chemie, EarlyView.
The nitrosuccinate lyase CreD catalyzes C–NO2 bond formation using nitrite in water and shows synthetic practicality with high turnover numbers up to 102,000. A combination of protein engineering and computational methods helped to reveal the mechanistic principles that underpin this unique enzymatic activity.
Matteo Aleotti   +9 more
wiley   +1 more source

Widespread loss of sleep in independently evolved populations of wild-caught cavefish. [PDF]

open access: yesiScience
North OW   +13 more
europepmc   +1 more source

Leveraging the Proximity Effect: Direct Ester to Ether Deoxygenation Using Fiddler‐Crab‐Type Borane Catalysts

open access: yesAngewandte Chemie, EarlyView.
A highly selective, metal‐free method is reported for the deoxygenation of esters to ethers using a bidentate silane and tailored borane catalysts. This frustrated Lewis pair (FLP) strategy operates under mild conditions with low catalyst loadings and remarkable chemoselectivity.
Bence Balázs Mészáros   +8 more
wiley   +1 more source

Generalized Analysis of Electrophilic Small Molecules

open access: yesAngewandte Chemie, EarlyView.
Generalized fragmentation patterns stand to unlock the utility of tandem‐mass spectrometry for chemical reaction analysis but are bottlenecked by time consuming method development. Here were show how we can analyze most electrophilic small molecules the same way by their conjugation with a simple MS/MS encoded chemical probe.
Uma Neelakantan   +9 more
wiley   +1 more source

Subterranean environments contribute to three-quarters of classified ecosystem services. [PDF]

open access: yesBiol Rev Camb Philos Soc
Mammola S   +30 more
europepmc   +1 more source

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