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Thermodynamic Properties of Cerium Oxalate and Cerium Oxide
Journal of the American Ceramic Society, 1985Differential scanning calorimetry and thermogravimetry were used to determine the thermodynamic properties of cerium oxalate. Hydrated cerium oxalate was found to contain 13 molecules of water and decomposed producing three thermal events corresponding to the loss of adsorbed water, water of hydration, and decomposition of anhydrous cerium oxalate to ...
SARAH ANN GALLAGHER +1 more
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The electronic state of cerium in thorium-cerium alloys
Journal of the Less Common Metals, 1962Abstract In spite of the fact that the atomic diameter of normal γ-cerium exceeds that of thorium, the lattice spacing/composition curve for the thorium-cerium system contains a minimum at approximately 26 at. % cerium. Possible reasons for this behaviour are discussed, and it is concluded that it is justifiable to regard the contraction of the ...
D.S Evans, G.V Raynor
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The Phase Diagram of the Cerium-Cerium Trichloride System
The Journal of Physical Chemistry, 1959The solubility of cerium in cerium trichloride is 9.3 mole% with a temperature coefficient of nearly zero between 777 and 950 deg C. The solubility of CeCl/sub 3/ in ceis not greater than 0.2 mole % at 950 EC. Above 777 deg C and 9.3 mole% added cerium the system consists of two immiscible liquids in equilibrium and has a consolute temperature that is ...
G. W. Mellors, S. Senderoff
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On the existence of cerium monocarbide: cerium nitride carbides
Journal of Inorganic and Nuclear Chemistry, 1969Abstract Re-examination of the binary system Ce-C gave no evidence for the existence of any phase structurally based on monatomic (methanide) anions, but the C22− anions of Ce2C3 appear to undergo reversible dissociation to methanide anions at high temperatures (1800–2000°C). The ternary system Ce-C-N is complex. Both tetragonal CeC2 and b.c.c. Ce2C3
J.S. Anderson, N.J. Clark, I.J. McColm
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Determination of the Cerium Oxidation State in Cerium Vanadate
Journal of the American Ceramic Society, 1995Use of low‐quality fuels in gas turbines can lead to vana‐dium hot corrosion of stabilized‐zirconia turbine blade coatings. The stabilizing oxide reacts with V 2 O 5 in the melt, forming a vanadate, thus removing the stabilizer from the zirconia.
Richard F. Reidy, Karen E. Swider
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Near Edge Structure in Cerium and Cerium Compounds
1983The L absorption spectra of γ- and α-Ce and of some Ce alloys have been measured. The L2 and L3 spectra show white lines. Those systems in which Ce is compressed exhibit an additional peak (α peak) above the white line. We deduce that α-Ce is not valence fluctuating and that the α peak in α-Ce is due to a core hole mediated excitation of the 4f ...
B. Lengeler, J. E. Müller, G. Materlik
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Cerium and cerium intermetallics: 4f-band metals?
Physica B+C, 1985Abstract The applicability of band theory to the description of the 4f electrons in Ce and its intermetallic compounds is considered. The convincing experimental and theoretical evidence that α-Ce is indeed a 4f-band metal, as first suggested by Gustafson and his collaborators, is reviewed, and the results of recent band calculations of the ground ...
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Nature Chemistry, 2013
Eric J. Schelter ponders on cerium's rather puzzling redox reactivity, and the varied practical applications that have emerged from it.
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Eric J. Schelter ponders on cerium's rather puzzling redox reactivity, and the varied practical applications that have emerged from it.
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Cerium and cerium oxide: A brief introduction
2020Scirè, Salvatore, Palmisano, Leonardo
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