Results 51 to 60 of about 43,467 (298)

Temperature‐Driven Emission Redistribution of Yb2+ in SrB4O7 Enables Highly Sensitive Optical Thermometry Supported by Multiple Linear Regression

Advanced Science, EarlyView.
A novel optical thermometer exploits the rare UV emission of Yb2+ ions in a SrB4O7 host, enabling highly sensitive, non‐contact temperature measurements from 80 to 420 K. The applied multiple linear regression (MLR) analysis results in a multiple increase in the resulting temperature sensitivity.
Fang Zhao, Teng Zheng, Przemysław Woźny, Miguel A. Hernández‐Rodríguez, Shiqing Xu, Inocencio R. Martín, Marcin Runowski   +6 more
wiley   +1 more source

CO2‐Induced Reverse Lattice Oxygen Spillover on Pt/CeO2 Enables Sulfur‐Resistant Dry Reforming of Methane

Angewandte Chemie, EarlyView.
A critical step, dry reforming of methane (DRM) converts biogas into useful syngas. Yet trace H2S in biogas rapidly poisons DRM catalysts, limiting practical use. We developed a robust Pt/CeO2 catalyst sustaining DRM activity via CO2‐induced reverse lattice oxygen spillover in H2S‐rich environments.
Jun Liu, Jiang Deng, Jiajia Zheng, Mohsen Beladi Mousavi, Chunning Sun, Jin Li, Xin Chen, Yongjie Shen, Haotian Huang, Ming Xie, Emiliano Cortés, Dengsong Zhang   +11 more
wiley   +2 more sources

Cerium-Based Metal–Organic Layers Catalyze Hydrogen Evolution Reaction through Dual Photoexcitation

, 2020
Cerium-based materials such as ceria are increasingly used in catalytic reactions. We report here the synthesis of the first Ce-based metal–organic layer (MOL), Ce6-BTB, comprising Ce6 secondary building units (SBUs) and 1,3,5-benzenetribenzoate (BTB ...
Justin S. Chen (6263132), Wenbin Lin (1264161), Xuanyu Feng (3307824), Kaiyuan Ni (1603651), Zhong Li (324520), Yang Song (88132), Yunhong Pi (4853488), Ziwan Xu (3997418)   +7 more
core   +1 more source

Tailored Synthesis of Doped Non‐Layered Oxide Nanosheets Using Designed Solid‐State Surfactants

Advanced Science, EarlyView.
This work reports a solid‐state surfactant templating method that enables precise doping of non‐layered oxide nanosheets. Using ceria and rare‐earth elements as model systems, we established design principles for solid‐state surfactants containing multiple elements.
Kentaro Ito, Eisuke Yamamoto, Kohei Hayashi, Daiki Kurimoto, Makoto Kobayashi, Minoru Osada   +5 more
wiley   +1 more source

Operando X-ray Fluorescence Analysis of Through-plane Cerium Ion Radical Quencher Migration in Polymer Electrolyte Fuel Cells

Electrochemistry
Polymer electrolyte fuel cells (PEFCs) need to achieve long-term durability for widespread commercialization. Chemical degradation of the perfluorosulfonic acid (PFSA) membrane caused by radical species (·OH) can be mitigated by adding cerium ions as ...
Aika TAKEZAWA, Yoichiro TSUJI, Takahiko ASAOKA, Maria OHKI, Oki SEKIZAWA, Kiyofumi NITTA, Yuki ORIKASA   +6 more
doaj   +1 more source

Discovery of the cerium isotopes [PDF]

Atomic Data and Nuclear Data Tables, 2009
The discovery of the 35 cerium isotopes discovered up to date is discussed. For each isotope a brief summary of the first refereed publication, including the production and identification method, is presented.
Ginepro, J. Q., Snyder, J., Thoennessen, M.   +2 more
openaire   +2 more sources

Oxygen Vacancy‐Enriched Platinum Single‐Atom Nanozyme Wrapped in Nanoislands: Unlocking Catalytic Activity and Reprogramming Redox Microenvironment for Osteonecrosis Repair

Advanced Science, EarlyView.
CeO2‐x/Pt single‐atom nano‐island is constructed via low‐temperature reduction, featuring abundant oxygen vacancies and an island–sea structure. It delivers outstanding multi‐enzyme‐mimetic activity and ROS‐scavenging efficiency. Density functional theory reveals optimized electronic structures and reaction pathways.
Yang Zhu, Zehui Lv, Xuejie Cai, Penghui Wei, Dengliang Wang, Zhao Wang, Ruoying Wang, Yingjie Wang, Xingdong Yang, Yixin Bian, Jiawei Xu, Xisheng Weng, Liangfeng Wei   +12 more
wiley   +1 more source

Enzyme‐Like Synthetic Cleft for Light‐Driven Water‐Oxidation Catalysis Via an Oxide Relay Pathway

Angewandte Chemie, EarlyView.
A carboxylic acid group introduced into the second coordination sphere of a Ru(bda) water oxidation catalyst forms a defined hydrogen bond within the catalytic cleft. This interaction locks the group in place and enables an intramolecular oxide relay pathway between Ru(V)═O and the carboxylate group, providing a distinct and efficient route for O─O ...
Daniel A. P. Friedewald, Gourab Das, Philipp H. Kirchner, Olga Anhalt, Deqi Tang, Sandra Luber, Florian Beuerle, Frank Würthner   +7 more
wiley   +2 more sources

Control of Membrane Fouling in Organics Filtration Using Ce-Doped Zirconia and Visible Light

Nanomaterials, 2019
Membrane fouling has been a major issue in the development of more efficient water treatment processes. Specifically in surface waters filtration, organic matter, such as humic-like substances, can cause irreversible fouling.
Fabrício Eduardo Bortot Coelho, Chiara Gionco, Maria Cristina Paganini, Paola Calza, Giuliana Magnacca   +4 more
doaj   +1 more source

Rare‐Earth Mediated Engineering in ZnSe@ZnS:Eu3+ to Simultaneously Achieve Structural Modulation and Atomic Eu Doping Sites for X‐Ray Imaging

Advanced Science, EarlyView.
A dual hard‐base anchoring strategy was developed to synthesize ZnSe@ZnS:Eu3+ quantum dots, leveraging fluoride‐oleylamine interactions to create surface atomic Eu doping sites. By precisely tuning temperature, Eu3+ concentration, and fluoride levels, we obtain morphologies ranging from tip growth to coupled flower‐like structures.
Jicun Ma, Chenhao Yang, Jiada Fan, Haorong Jiao, Jiawang Liu, Jialiang Xu, Hui Cai, Yinghui Wang, Boyuan Shen, Jiabin Cui   +9 more
wiley   +1 more source