Results 141 to 150 of about 4,166 (227)

A Crystalline and Thermally Stable Selenocysteine Selenenic Acid

Angewandte Chemie, Volume 138, Issue 32, 3 August 2026.
The long‐sought catalytic intermediate of selenoproteins, selenocysteine selenenic acid (Sec–SeOH), is isolated for the first time at ambient temperature. A bioinspired selenopeptide sequence encapsulated within a protective molecular cradle and an oxidant‐free route from selenenyl iodide (Sec–SeI) enable the isolation of Sec–SeOH. Contrary to the long‐
Ryosuke Masuda, Satoru Kuwano, Kei Goto
wiley   +2 more sources

Alkali Chalcogenido Dialuminates A 6[Al2 Q 6] (A = K, Rb, Cs; Q = S, Se, Te)

Zeitschrift für anorganische und allgemeine Chemie, EarlyView.
Seven new alkali chalcogenido aluminates A6[Al2Q6] (A = K‐Cs, Q = S‐Te) complement the family of simple metallates(III) A6[M2Q6] (M = Al‐In, FeIII) with dinuclear anions of two edge sharing [AlQ4] tetrahedra. Despite the similar anions, straightforward bonding situation and physical properties, these metallates crystallize in seven different structure ...
Michael Schwarz, Vincent Daiber, Caroline Röhr   +2 more
wiley   +1 more source

Isolation and Structural Elucidation of the Pnictogen Polysulfate Compounds As2[S2O7]2[S3O10] and [SeCl3][Pn(S2O7)2] (Pn = Sb, Bi)

Zeitschrift für anorganische und allgemeine Chemie, EarlyView.
The isolation and solid‐state structures of the two disulfate‐containing pnictogenates [SeCl3][Pn(S2O7)2] (Pn = Sb, Bi), as well as the mixed‐anionic As2[S2O7]2[S3O10] are presented. The former two consist of complex ∞1{[Pn(S2O7)1/1t(S2O7)2/2e]‐}$$ {\infty }^{1}\left\{{\left[\mathrm{Pn}{\left({\mathrm{S}}_{2}{\mathrm{O}}_{7}\right)}_{1/1}^{\mathrm{t}}{\
Jan Langwald, Luisa Ebels, Marios Symeonidis, Jörn Bruns, Antonio Frontera, Mathias S. Wickleder   +5 more
wiley   +1 more source

S‐Adenosylmethionine (SAM) hydrolases counter increased SAM epimerisation in thermophilic archaea

The FEBS Journal, EarlyView.
S‐Adenosyl‐l‐methionine (SAM) is a vital enzyme cofactor. Epimerisation at the sulfonium centre of biologically active (SS,SCα)‐SAM is driven by heat, yielding biologically inactive (RS,SCα)‐SAM. Here, two novel archaeal SAM hydrolases from the thermophilic Sulfolobus acidocaldarius and the halophilic Haloferax volcanii are shown to cleave (RS,SCα)‐SAM.
Agnes Bartels, Michael K. F. Mohr, Phillip Nußbaum, Marie Joest, Bianca Wassmer, Laurent Rasquin, Sonja‐Verena Albers, Jennifer N. Andexer   +7 more
wiley   +1 more source

Room Temperature Wafer‐Scale Synthesis of Highly Transparent and Conductive p‐Type Sulfur‐Doped Copper Iodide

ENERGY &ENVIRONMENTAL MATERIALS, Volume 9, Issue 5, September 2026.
Wafer‐scale, room temperature synthesis of S‐doped CuI achieves high‐performance transparent p‐type electrodes. Pre‐doping enables precise control of crystallinity and hole density, yielding 86% transmittance and 75 Ω sq−1 sheet resistance. A record‐high figure of merit of 95 000 MΩ−1 and excellent flexibility across diverse substrates are demonstrated.
Sungsan Kang, Taehun Kim, Min Jung, Jinhyeok Pyo, Sohyeon Park, Seonyou Park, Junsung Byeon, Hui Gu Lee, Jin Pyo Hong, Sung‐Tae Lee, Minseok Kim, Hyoungsoon Lee, SeungNam Cha, Sangyeon Pak   +13 more
wiley   +1 more source

Ionothermal Synthesis of Cu(Sb2Se3)[AlCl4] and Cu5(Bi2Se3)6[AlCl4]5 : Monolayers of Sb2Se3 and Bi2Se3 Stabilized by Cu[AlCl4]

Zeitschrift für anorganische und allgemeine Chemie, Volume 652, Issue 12, 3 August 2026.
Ionothermal synthesis in Lewis‐acidic ionic liquids (ILs) yields two new low‐dimensional pnictogen–selenide networks cocrystallized with Cu[AlCl4]. Both are narrow‐gap semiconductors that exhibit strong absorption throughout the visible range. Topochemical AlCl3 extraction triggers partial delamination, pointing to a viable route toward 2D derivatives.
Oliver Dreimann, Vitaliy Romaka, Michael Ruck   +2 more
wiley   +1 more source

From Behavior to Dynamics: Decoding Carrier Roles in Cu‐based Photocathodes for Solar‐Driven CO2 Reduction

Advanced Materials, Volume 38, Issue 44, 7 August 2026.
The performance of Cu‐based photocathodes in photoelectrochemical CO2 reduction is not governed by catalytic sites alone, but by the dynamic journey of photogenerated carriers. This review decodes how carrier generation, recombination, transport, accumulation, extraction, and electrolyte coupling shape catalytic activity, selectivity, and stability ...
Yi‐Cheng Wang, Chenyu Xu, Peng‐Fei Sui, Yi Liu, Xiaolei Wang, Jing‐Li Luo   +5 more
wiley   +1 more source

First‐Principles Investigation of the Structural, Electronic, Optical, Elastic, and Thermal Properties of Defect Diamond‐Like Hg3P2S8

Advanced Physics Research, Volume 5, Issue 8, August 2026.
The defect diamond‐like material Hg3P2S8 (HPS) is systematically investigated using first‐principles methods to reveal the interplay between highly distorted HgS4 and rigid PS4 units. The HPS material exhibits a strong anisotropic second‐harmonic generation (SHG) response, favorable optical properties, and low thermal conductivity, highlighting its ...
Saravana Karthikeyan SKS, Sankar Ganesh Ramaraj, Ryo Watanabe, Choji Fukuhara, Chang Yi Kong   +4 more
wiley   +1 more source

Selenium‐Containing 1,4‐Naphthoquinone Derivatives Trigger Reactive Oxygen Species and Apoptosis in Triple‐Negative Breast Cancer Cells

Drug Development Research, Volume 87, Issue 5, August 2026.
ABSTRACT Cancer ranks as a leading cause of death worldwide, demanding new affordable therapies. Nature offers a diverse array of bioactive scaffolds, including 1,4‐naphthoquinone, which serves as a precursor for numerous natural and synthetic compounds with potent antitumor properties.
Eduardo Angulo‐Elizari, Asif Raza, Hannah Johnson, Nuria Martínez‐Sáez, Ignacio Encío, Arun K. Sharma, Carmen Sanmartín, Daniel Plano   +7 more
wiley   +1 more source

Boosting electrocatalytic performance of cobalt iron telluride via vanadium doping for enhanced water and urea electrolysis

InfoMat, Volume 8, Issue 8, August 2026.
This study employs a heteroatom doping strategy to synthesize V‐doped CoFeTe2 catalysts, achieving remarkable HER, OER, UOR, and overall water‐splitting performance. The enhanced activity is attributed to an optimized electronic structure and improved intermediate binding characteristics.
Jagadis Gautam, Seul‐Yi Lee, Soo‐Jin Park   +2 more
wiley   +1 more source