Results 51 to 60 of about 4,166 (227)

Neuromorphic Electronics for Intelligence Everywhere: Emerging Devices, Flexible Platforms, and Scalable System Architectures

Advanced Materials, EarlyView.
The perspective presents an integrated view of neuromorphic technologies, from device physics to real‐time applicability, while highlighting the necessity of full‐stack co‐optimization. By outlining practical hardware‐level strategies to exploit device behavior and mitigate non‐idealities, it shows pathways for building efficient, scalable, and ...
Kapil Bhardwaj, Roshni Satheesh Babu, Yuxin Xia, Eva Bestelink, Radu Sporea, Nikos Hastas, Ioannis Zeimpekis, Dimitra G. Georgiadou, Sayani Majumdar   +8 more
wiley   +1 more source

Clustomesogen Showing Sub‐Zero Liquid Crystal Properties: Supramolecular Assembly Between Cs2[Mo6Ii8(OCOC2F5)6] and Hexaethylenoxide Containing Mesogenic Dimers

Advanced Materials, EarlyView.
Associating a red‐NIR phosphorescent octahedral hexanuclear molybdenum cluster compound with hexaethyleneoxide chains bearing mesogenic units on both ends leads to an emissive hybrid liquid crystal showing mesomorphism on a very unusual temperature range down to −25°C.
Killiann Heinz, Jeanne Rebours, Zoulikha Zerrouqi, Noée Dumait, Maria Amela‐Cortes, Nikolai Scheuring, Sara Simonovska, Sebastian Marino, Max Ebert, Stéphane Cordier, Sabine Laschat, Yann Molard   +11 more
wiley   +1 more source

Thiosulfoxide (Sulfane) Sulfur: New Chemistry and New Regulatory Roles in Biology

Molecules, 2014
The understanding of sulfur bonding is undergoing change. Old theories on hypervalency of sulfur and the nature of the chalcogen-chalcogen bond are now questioned.
John I. Toohey, Arthur J. L. Cooper
doaj   +1 more source

Understanding the catalysis by bis-selenonium cations as bidentate chalcogen bond donors

Tetrahedron Chem, 2022
The mode of activation and catalysis of bidentate bis-selenonium cations have been computationally explored in detail by means of Density Functional Theory calculations.
Susana Portela, Israel Fernández
doaj   +1 more source

Thermodynamics of Anion Binding by Chalcogen Bonding Receptors [PDF]

Chemistry – A European Journal, 2018
AbstractThe application of chalcogen bonding (ChB) to anion recognition is an underdeveloped area of host–guest supramolecular chemistry. The chemical instability of heavier chalcogen derivatives may in part be responsible for the lack of progress. Herein, the synthesis of a new structurally simple, tellurium‐based ChB binding motif is reported, the ...
Jason Y. C. Lim, Jane Y. Liew, Paul D. Beer   +2 more
openaire   +2 more sources

MOCVD‐Grown MoS2 Wafers as a Transfer‐Free Platform for Top‐Gate Devices via Dry Interface Engineering

Advanced Materials, EarlyView.
We reveal the electronic origin of hidden interfacial doping in monolayer MoS2 grown by MOCVD, identifying sulfate related and water like species as intrinsic donors. Through dry interface engineering approach, we demonstrate MOCVD‐grown single‐crystal MoS2 wafers as a transfer‐free platform for the reliable evaluation of intrinsic gate stacks and ...
Shuhong Li, Juiteng Chang, Keisuke Atsumi, Kosei Matsumoto, Itsuki Tanaka, Tomonori Nishimura, Kaito Kanahashi, Takahiro Nagata, Jun Nara, Yoshiki Sakuma, Emi Kano, Nobuyuki Ikarashi, Kosuke Nagashio   +12 more
wiley   +1 more source

Photo‐ and Thermally‐Induced Huge Layer Decoupling in Twisted Bilayer WSe2

Advanced Materials, EarlyView.
A newly developed automated dark‐field tomography visualizes twist‐angle‐dependent structural relaxation and quantifies 3D structures in twisted bilayer WSe2. This approach reveals the evolution of local stacking configurations, thermally induced sub‐ångström interlayer decoupling, and light‐driven interlayer expansion on picosecond timescales ...
A. Nakamura, Y. Chiashi, T. Shimojima, Y. Tanaka, S. Akatsuka, M. Sakano, S. Masubuchi, T. Machida, K. Watanabe, T. Taniguchi, K. Ishizaka   +10 more
wiley   +1 more source

Far‐Infrared Hyperbolic Phonon–Polaritons in Zirconium Disulfide

Advanced Materials, EarlyView.
An unpatterned ZrS2${\rm ZrS}_2$ flake, coupled to far‐field infrared light by metal nanoribbons, reveals hyperbolic phonon polaritons with multiple higher‐order branches and effective refractive indices up to 223. This resonator‐assisted approach establishes ZrS2${\rm ZrS}_2$ as a compact van der Waals platform for deeply subwavelength far‐infrared ...
Subhodip Saha, Ryan Kowalski, Joseph R. Matson, Thomas G. Folland, Tony Low, Joshua D. Caldwell, In‐Ho Lee, Sang‐Hyun Oh   +7 more
wiley   +1 more source

Chalcogen bonding in the solid-state structures of 1,3-bis(benzimidazoliumyl)benzene-based chalcogen-bonding donors

Acta Crystallographica Section C Structural Chemistry, 2023
1,3-Bis(benzimidazoliumyl)benzene-based chalcogen-bonding catalysts were previously successfully applied in different benchmark reactions. In one of those examples, i.e. the activation of quinolines, sulfur- and selenium-based chalcogen-bonding catalysts showed comparable properties, which is unexpected, as the selenium-containing catalysts should show
Tim Steinke, Elric Engelage, Stefan M. Huber   +2 more
openaire   +2 more sources

Escaping the Scaling Relationships in Oxygen Reduction Catalysis: Implications for PEM Fuel Cells

Advanced Materials, EarlyView.
Escaping the scaling relationships of the oxygen reduction reaction is vital for hydrogen fuel cells. This outlook examines how interfacial heterogeneity, spanning the subsurface lattice, chemisorption layer, and near‐interface solvation volume, mechanistically decouples intermediate binding energetics.
Muhammad Bilal Wazir, Lourdes F. Vega, Maryam Khaleel   +2 more
wiley   +1 more source