Results 101 to 110 of about 3,178 (211)

Synthesis and Supramolecular Organization of para-Carboxyhydrazinylidene Derivative of 3-Nitrophenylthiazolo[3,2-a]pyrimidine

open access: yesChemistry Proceedings
Synthesis of para-carboxyhydrazinylidene, the derivative of 3-nitrophenylthiazolo[3,2-a]pyrimidine, was successfully performed with good yields. It was established that different types of non-covalent intermolecular interaction may influence the ...
Dilyara O. Mingazhetdinova   +6 more
doaj   +1 more source

chalcogen bond

open access: yes
Citation: 'chalcogen bond' in the IUPAC Compendium of Chemical Terminology, 5th ed.; International Union of Pure and Applied Chemistry; 2025. Online version 5.0.0, 2025. 10.1351/goldbook.09631 • License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International for individual terms. Requests for commercial
openaire   +1 more source

Taming a Blue Gas—Structure and Chemistry of Hexafluorothioacetone

open access: yesAngewandte Chemie International Edition, EarlyView.
Hexafluorothioacetone (1), a blue gas at r.t., was synthesized by flash vacuum pyrolysis of its cyclic dimer at 660°C. We discuss fundamental properties of elusive 1, including single‐crystal structure and nuclear magnetic resonance spectroscopy, despite its tendency to dimerize even at –74°C.
Hennes Günther   +3 more
wiley   +1 more source

Supramolecular Chalcogen‐Bonded Shape Memory Actuators

open access: yesAngewandte Chemie
Abstract Supramolecular liquid crystal elastomers (LCEs) incorporating chalcogen bonds (ChBs) have been synthesized and investigated for shape memory and actuation properties. LCEs featuring strong Se⋯N ChBs (−40 to −43 kJ mol −1 ) exhibit both shape memory effects (SME) and
Hongshuang Guo   +5 more
openaire   +3 more sources

Catalytic Sulfur‐Atom Transfer Enabled by a Bis(disulfide) Titanium Complex

open access: yesAngewandte Chemie International Edition, EarlyView.
Multi‐electron transformations with titanium are underexplored due to limited access to low‐valent precursors. The four‐electron activation of elemental sulfur by a Ti(IV) complex yields a rare titanium bis(disulfide) complex, enabling the efficient catalytic synthesis of isothiocyanates from isonitriles under mild conditions.
Sebastian Samir Cremer   +3 more
wiley   +1 more source

The roles of side chains in Y6‐series non‐fullerene acceptors for high‐performance organic solar cells

open access: yesBulletin of the Korean Chemical Society, EarlyView.
The development of organic solar cells (OSCs) has been driven by structural modifications of Y6‐series non‐fullerene acceptors. In particular, side‐chain engineering regulates solubility, molecular packing, and energy levels, enabling efficiencies to increase from 15.7% to over 20%.
Peddaboodi Gopikrishna   +3 more
wiley   +1 more source

Diamondoids Under Pressure

open access: yesGeophysical Monograph Series, Page 341-349., 2020

This book is Open Access. A digital copy can be downloaded for free from Wiley Online Library.

Explores the behavior of carbon in minerals, melts, and fluids under extreme conditions

Carbon trapped in diamonds and carbonate-bearing rocks in subduction zones are examples of the continuing exchange of substantial carbon ...
Sulgiye Park, Yu Lin, Wendy L. Mao
wiley  

+1 more source

Infinite Functional Versatility, Formidable Limits: Evaluating Gallium‐Based Liquid Metals in Rechargeable Batteries

open access: yesCarbon Energy, EarlyView.
Beyond the hype surrounding the self‐healing properties of gallium‐based liquid metals (Ga‐LMs), this perspective critically examines their functional roles in metal‐ion batteries, highlighting both their underlying merits and the often‐overlooked challenges, including non‐representative design and testing configurations, performance overestimations ...
Turly P. P. Sumanasekara   +7 more
wiley   +1 more source

Atom Swapping Reaction on Diborylcarbenoid: Synthesis and Electronic Structure of Inorganic Chalcogenophene Analogues

open access: yesChemistry – A European Journal, EarlyView.
ABSTRACT Inorganic analogues of aromatic compounds, wherein C═C bonds are replaced with B─N bonds, are isoelectronic with the original aromatic compounds, however, they can show different properties. While borazine, an inorganic analogue of benzene, has been well‐studied, inorganic analogues of chalcogenophene have been less explored.
Yuki Shibutani   +3 more
wiley   +1 more source

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